高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力

引用本文: 王宪中, 康万利, 孟祥灿, 范海明, 徐海, 黄经纬, 傅建斌, 张一诺. 高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力[J]. 物理化学学报, 2012, 28(10): 2285-2290. doi: 10.3866/PKU.WHXB201206291 shu

Citation: WANG Xian-Zhong, KANG Wan-Li, MENG Xiang-Can, FAN Hai-Ming, XU Hai, HUANG Jing-Wei, FU Jian-Bin, ZHANG Yi-Nuo. Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants[J]. Acta Physico-Chimica Sinica, 2012, 28(10): 2285-2290. doi: 10.3866/PKU.WHXB201206291 shu

高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力

基金项目:
山东省&ldquo

泰山学者&rdquo

建设工程(ts20070704) (ts20070704)

国家自然科学基金(51104169) (51104169)

山东省自然科学基金(ZR2010BQ003, ZR2010EZ006)与中央高校基本科研业务费专项资金(11CX06028A)资助项目 (ZR2010BQ003, ZR2010EZ006)与中央高校基本科研业务费专项资金(11CX06028A)

摘要:

研究了在高盐油藏中, 利用两性/阴离子表面活性剂的协同效应获得油水超低界面张力的方法. 两性表面活性剂十六烷基磺基甜菜碱与高盐矿化水具有很好的相容性, 但在表面活性剂浓度为0.07%-0.39%(质量分数)范围内仅能使油水界面张力达到10^-2 mN·m^-1量级, 加入阴离子表面活性剂十二烷基硫酸钠后则可与原油达到超低界面张力. 通过探讨表面活性剂总浓度、金属离子浓度、复配比例对油水动态界面张力的影响, 发现两性/阴离子表面活性剂混合体系可以在高矿化度、低浓度和0.04%-0.37%的宽浓度范围下获得10^-5 mN·m^-1量级的超低界面张力, 并分析了两性/阴离子表面活性剂间协同获得超低界面张力的机制.

关键词:

English

Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants

1.
College of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266555, Shandong Province, P. R. China
Received Date: 07 May 2012
Available Online: 26 September 2012
Fund Project:
山东省&ldquo

泰山学者&rdquo

建设工程(ts20070704)

国家自然科学基金(51104169)

山东省自然科学基金(ZR2010BQ003, ZR2010EZ006)与中央高校基本科研业务费专项资金(11CX06028A)资助项目

Abstract:

The present work investigates the use of synergistic interactions between zwitterionic and anionic surfactants to obtain ultra-low interfacial tension (IFT) in a high salinity reservoir. Zwitterionic surfactant N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate was found to be compatible with simulated high salinity water, reducing crude oil/water interfacial tension to a magnitude of 10^-2 mN·m^-1 in a surfactant concentration range of 0.07%-0.39% (mass fraction), whereas ultra-low IFT was obtained by adding anionic surfactant sodium dodecyl sulfate. Furthermore, the effects of total surfactant concentration, metal ion concentration, and molar ratio on the dynamic interfacial tension of zwitterionic/anionic surfactant mixtures were studied. Results showed that 10^-5 mN·m^-1 magnitude ultra-low IFT was obtained over a wide range of surfactant concentrations from as low as 0.04% and up to 0.37% in high salinity water. The synergistic mechanism of ultra-low IFT formed in zwitterionic/anionic surfactant systems was further analyzed.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力

English

Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力

English

Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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