三维配位聚合物[Sr(BDC)(H<sub>2</sub>O)]的合成、结构与热稳定性

引用本文: 付颖, 李国宝, 廖复辉, 林建华. 三维配位聚合物[Sr(BDC)(H₂O)]的合成、结构与热稳定性[J]. 物理化学学报, 2011, 27(10): 2269-2274. doi: 10.3866/PKU.WHXB20110908 shu

Citation: FU Ying, LI Guo-Bao, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)][J]. Acta Physico-Chimica Sinica, 2011, 27(10): 2269-2274. doi: 10.3866/PKU.WHXB20110908 shu

三维配位聚合物[Sr(BDC)(H₂O)]的合成、结构与热稳定性

基金项目:
国家重大基础研究计划(973) (2010CB833103)资助项目 (973) (2010CB833103)

摘要: 利用溶剂热法在硝酸锶、1,4-对苯二甲酸(BDC)、N,N'-二甲基甲酰胺(DMF)和水体系中合成了一种新的配位聚合物[Sr(BDC)(H₂O)] (1), 并通过单晶X射线衍射、变温粉末X射线衍射、元素分析、红外光谱和热重-质谱联用对其进行了表征. 该化合物属正交晶系的Pbca 空间群, 晶胞参数为a=1.1854(2) nm, b=0.7122(1) nm,c=2.0031(4) nm. 该化合物具有三维网络结构, 由共面的SrO₈四方反棱柱组成的zigzag 链通过1,4-对苯二甲酸配体连接而成. 热重-质谱联用和变温粉末X射线衍射分析表明它的骨架具有较高的热稳定性.

关键词:

English

Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]

1.
Beijing National Laboratory for Molecular Sciences BNLMS, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Received Date: 20 May 2011
Available Online: 27 September 2011
Fund Project:
国家重大基础研究计划(973) (2010CB833103)资助项目

Abstract: The solvothermal reactions of Sr(NO₃)₂ with 1,4-benzenedicarboxylic acid (BDC) in a mixture of H₂O/N,N'-dimethylformamide (DMF) resulted in a novel coordination polymer, [Sr(BDC) (H₂O)] (1), which was characterized by single crystal and variable temperature powder X-ray diffraction (VTPXRD), elemental analysis, infra-red (IR) spectroscopy, and thermogravimetric-mass spectrometric (TG-MS) analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with a=1.1854(2) nm, b=0.7122 (1) nm, and c=2.0031(4) nm. It is a three-dimensional (3D) framework consisting of zigzag chains that are formed by face-shared SrO₈ square antiprisms and bridging BDC ligands. TG-MS and VTPXRD studies revealed that the framework of compound 1 exhibited a high thermal stability.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

三维配位聚合物[Sr(BDC)(H₂O)]的合成、结构与热稳定性

English

Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]

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中国化学会秘书处

三维配位聚合物[Sr(BDC)(H2O)]的合成、结构与热稳定性

English

Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H2O)]

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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中国化学会秘书处

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Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]

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