引用本文:
罗仁生, 阎江丽, 毛希安. 用2D NMR研究锡配合物配体的交换反应[J]. 物理化学学报,
1997, 13(10): 925-928.
doi:
10.3866/PKU.WHXB19971012
Citation: Luo Ren-Sheng, Yan Jiang-Li, Mao Xi-An. Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR[J]. Acta Physico-Chimica Sinica, 1997, 13(10): 925-928. doi: 10.3866/PKU.WHXB19971012
Citation: Luo Ren-Sheng, Yan Jiang-Li, Mao Xi-An. Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR[J]. Acta Physico-Chimica Sinica, 1997, 13(10): 925-928. doi: 10.3866/PKU.WHXB19971012
用2D NMR研究锡配合物配体的交换反应
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关键词:
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双核锡(IV)配合物
- / 二维交换谱
- / 交换速率常数
English
Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR
Abstract:
Two-dimensional 1H exchange spectroscopy was applied to study of the ligand exchange kinetics of the complex [Sn2(μ-OH)2Cl6(DMF)2]•4DMF in DMF-d7 solution. The exchange rate constants for the ligand H2O and DMF between free and coordination states were evaluated.
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Key words:
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Sn(IV) complex
- / 2D EXSY
- / Exchange rate constants
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