引用本文:
李红志, 李强, 朱起鹤, 孔繁敖. 紫外光激励产生高振动激发ν1模的NO2分子[J]. 物理化学学报,
1996, 12(04): 382-384.
doi:
10.3866/PKU.WHXB19960420
Citation: Li Hong-Zhi, Li Qiang, Zhu Qi-He, Kong Fan-Ao. Formation of High Vibrational ν1 States of NO2(X2,A1) Excited at 308nm[J]. Acta Physico-Chimica Sinica, 1996, 12(04): 382-384. doi: 10.3866/PKU.WHXB19960420
Citation: Li Hong-Zhi, Li Qiang, Zhu Qi-He, Kong Fan-Ao. Formation of High Vibrational ν1 States of NO2(X2,A1) Excited at 308nm[J]. Acta Physico-Chimica Sinica, 1996, 12(04): 382-384. doi: 10.3866/PKU.WHXB19960420
English
Formation of High Vibrational ν1 States of NO2(X2,A1) Excited at 308nm
Abstract:
The photon-excited NO2 at 308 nm has been investigated by Time-Resolved FTIR spectroscopy. The IR fluorescence from highly excited NO2(X2 A1) in ν1 vibrational mode has been observed. These excited states are resulted from the strong vibronic mixing of electronic excited A2 B2/B2 B1 states with the ground X2 A1 state. It is considered that symmetric stretching ν1 mode is reserved from the photolysis because its vibrational style is unsuitable for dissociation.
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Key words:
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IR emission spectroscopy
- / Highly excited vibrational state
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