引用本文:
黄维, 俞启全, 金韵. CeO2/SiO2的制备及丁烯异构化动力学[J]. 物理化学学报,
1995, 11(01): 9-14.
doi:
10.3866/PKU.WHXB19950103
Citation: Huang Wei, Yu Qi-Quan, Jin Yun. Preparation of CeO2/SiO2 and Kinetics of Isomerization of Butene[J]. Acta Physico-Chimica Sinica, 1995, 11(01): 9-14. doi: 10.3866/PKU.WHXB19950103
Citation: Huang Wei, Yu Qi-Quan, Jin Yun. Preparation of CeO2/SiO2 and Kinetics of Isomerization of Butene[J]. Acta Physico-Chimica Sinica, 1995, 11(01): 9-14. doi: 10.3866/PKU.WHXB19950103
CeO2/SiO2的制备及丁烯异构化动力学
English
Preparation of CeO2/SiO2 and Kinetics of Isomerization of Butene
Abstract:
Catalysts, CeO2/SiO2, were prepared by the impregnated method. The activity of the catalysts at calcination temperature of the catalysts in the range 300-500 ℃ was constant and decreased at 600℃. The catalystic activity in the range of ratio of CeO2 to SiO2, 1/5-1/32, increased linearly. The reaction order with respect to t-2-butene or c-2-butene was first proximate1y at low partial pressures of t-2-butene or c-2-butene.At higher partial pressures of t-2-butene or c-2-butene the kinetics of isomerization of 1-butene. The kinetic parameters were estimated by methods of ortho nal design. The estimated values of adsorption of 1-butene, t-2-butene and c-2-butene are coincided with the experimental values by the pulse method.
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Key words:
-
CeO2/SiO2
- / Kinetics
- / L-H equation
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