Citation: Li Jing-Jian, Diao Peng, Cai Sheng-Min, Hou Yong-Tian, Wang Xin, Zhang Shu-Lin. The Influence of Chmical Oxidation on Surface State and Photoluminescence of Porous Silicon[J]. Acta Physico-Chimica Sinica, 1994, 10(08): 737-740. doi: 10.3866/PKU.WHXB19940814
English
The Influence of Chmical Oxidation on Surface State and Photoluminescence of Porous Silicon
The changes in photoluminescence and FTIR spectra of porous silicon subjected to oxidation were examined. With the increase of oxidizing duration, the relative amount of the Si-H2 surface species on PS decreases even though the photoluminescence intensity increases. the result suggests that it isn't SiH2 but Si-O and Si-O-Si on the interface of PS play a key role in enhancing the photoluminescence. A complete photoluminescence mechanism should consider the influence of surface state of porous silicon based on the quantum confinement effect model.
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