引用本文:
林华宽, 周志芬, 古宗信, 陈荣悌. 镍(II)同α-氨基酸及草酸根生成二元配合物的热力学及热化学研究所[J]. 物理化学学报,
1991, 7(01): 82-86.
doi:
10.3866/PKU.WHXB19910113
Citation: Lin Hua-Kuan, Zhou Zhi-Fen, Gu Zong-Xin, Chen Rong-Ti. Thermodynamic and Calorimetric Study on the Formation of Binary Complex Compounds of Nickel(II) with some α-Amino Acids and Oxalate[J]. Acta Physico-Chimica Sinica, 1991, 7(01): 82-86. doi: 10.3866/PKU.WHXB19910113
Citation: Lin Hua-Kuan, Zhou Zhi-Fen, Gu Zong-Xin, Chen Rong-Ti. Thermodynamic and Calorimetric Study on the Formation of Binary Complex Compounds of Nickel(II) with some α-Amino Acids and Oxalate[J]. Acta Physico-Chimica Sinica, 1991, 7(01): 82-86. doi: 10.3866/PKU.WHXB19910113
镍(II)同α-氨基酸及草酸根生成二元配合物的热力学及热化学研究所
摘要:
在25.0±0.1 ℃及0.1 mol·dm~(-3)(KNO_3)的条件下应用pH法测定了镍(Ⅱ)与L-脯氨酸。L-缬氨酸,α-氨基异丁酸和草酸根生成二元配合物的稳定常数。并在相同条件下用量热法测定了这些二元配合物的生成热及草酸根的质子化热。对草酸根的质子化热的吸热机理进行了初步的理论探讨。
English
Thermodynamic and Calorimetric Study on the Formation of Binary Complex Compounds of Nickel(II) with some α-Amino Acids and Oxalate
Abstract:
The stability constants of binary complex compounds of nickel (Ⅱ) with Lproline, L-valine, α-aminoisobutyric acid and oxalate were determined at 25.0±0.1 ℃, Ⅰ=0.1 mol·dm~(-3) (KNO_3) by pH method. The heats of formation of these binary systems and the heat of protonation of oxalate were determined by calorimetry under the same conditions. The fact that the heat effect of protonation of oxalate was found to be endothermic can be interpreted on account of the existence of seven membered ring of oxalate formed in aqueous solution through hydrogen bonds with water molecule.
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