引用本文:
徐筱杰, 关烨弟, 尚振海, 关玥, 唐有祺. R、S双[N-(5-氯邻羟苯亚甲基)-α-苯乙胺]合钯(Ⅱ)的晶体结构及分子绝对构型[J]. 物理化学学报,
1985, 1(06): 575-578.
doi:
10.3866/PKU.WHXB19850612
Citation: Xu Xiaojie, Guan Yedi, Shang Zhenhai, Guan Yue, Tang Youqi. THE CRYSTAL STRUCTURE AND MOLECULAR ABSOLUTE CONFIGURATIONS OF BIS [N-(5-CHLORO-OXID-BENZYLIDENE)-α-PHENYLETHYLAMINE] PALLADIUM(Ⅱ)[J]. Acta Physico-Chimica Sinica, 1985, 1(06): 575-578. doi: 10.3866/PKU.WHXB19850612
Citation: Xu Xiaojie, Guan Yedi, Shang Zhenhai, Guan Yue, Tang Youqi. THE CRYSTAL STRUCTURE AND MOLECULAR ABSOLUTE CONFIGURATIONS OF BIS [N-(5-CHLORO-OXID-BENZYLIDENE)-α-PHENYLETHYLAMINE] PALLADIUM(Ⅱ)[J]. Acta Physico-Chimica Sinica, 1985, 1(06): 575-578. doi: 10.3866/PKU.WHXB19850612
R、S双[N-(5-氯邻羟苯亚甲基)-α-苯乙胺]合钯(Ⅱ)的晶体结构及分子绝对构型
English
THE CRYSTAL STRUCTURE AND MOLECULAR ABSOLUTE CONFIGURATIONS OF BIS [N-(5-CHLORO-OXID-BENZYLIDENE)-α-PHENYLETHYLAMINE] PALLADIUM(Ⅱ)
Abstract:
The title compound crystallizes in orthorhombic crystal system with space group P 2_12_12_1, α=0.8983(4) nm, b=1.7538(9) nm, c=1.7603(16) nm and z=4. The crystal structure were solved by direct method. Molecular absolute configurations for two enantiomeric structures were determined by anomalous scattering of Pd~(++) for CuKα radiation. The final R factors are 0.050 for R-(+)-structureand 0.051 for S-(-)-structure.
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