引用本文:
冯驸, 崔治财, 段正超, 胡卫兵. 1,1-二苄基-1,1-二硫乙酰腙甲烷类化合物的微波辐射法合成[J]. 应用化学,
2012, 29(11): 1251-1255.
doi:
10.3724/SP.J.1095.2012.00547
Citation: FENG Fu, CUI Zhicai, DUAN Zhengchao, HU Weibing. Synthesis of 1, 1-Bibenzyl-1, 1-bimercaptoacetyl-hydrazonemethane under Microwave Irradiation[J]. Chinese Journal of Applied Chemistry, 2012, 29(11): 1251-1255. doi: 10.3724/SP.J.1095.2012.00547
Citation: FENG Fu, CUI Zhicai, DUAN Zhengchao, HU Weibing. Synthesis of 1, 1-Bibenzyl-1, 1-bimercaptoacetyl-hydrazonemethane under Microwave Irradiation[J]. Chinese Journal of Applied Chemistry, 2012, 29(11): 1251-1255. doi: 10.3724/SP.J.1095.2012.00547
1,1-二苄基-1,1-二硫乙酰腙甲烷类化合物的微波辐射法合成
English
Synthesis of 1, 1-Bibenzyl-1, 1-bimercaptoacetyl-hydrazonemethane under Microwave Irradiation
Abstract:
Using 1,3-diphenylacetone as precursor,bibenzyldithiolmethane(1) was prepared through reacting 1,3-diphenylacetone with dry hydrogen sulfide and hydrogen chloride.Under microwave irradiation,compound 1 was subjected to esterification and hydrazinolysis to yield 1,1-bibenzyl-1,1-bimercaptoacetyl-hydrazine(3).The condensation reactions between compound 3 and aromatic aldehyde led to the production of a series of 1,1-bibenzyl-1,1-bimercaptoacetylhydrazone(4a~4n).Their structures were confirmed by IR,1H NMR,MS and elemental analysis.
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Key words:
- microwave irradiation
- / acetylhydrazone
- / synthesis
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