引用本文:
王洪, 杨驰, 郭春泰, 王大兴, 孙礼安. 表面包覆保护的离子电池新型正极材料LiFeBO3电化学性能[J]. 应用化学,
2011, 28(7): 821-825.
doi:
10.3724/SP.J.1095.2011.00522
Citation: WANG Hong, YANG Chi, GUO Chuntai, WANG Daxing, SUN Lian. The Electrochemical Performance of Surface Protected LiFeBO3 Cathode Materials for Li-ion Batteries[J]. Chinese Journal of Applied Chemistry, 2011, 28(7): 821-825. doi: 10.3724/SP.J.1095.2011.00522
Citation: WANG Hong, YANG Chi, GUO Chuntai, WANG Daxing, SUN Lian. The Electrochemical Performance of Surface Protected LiFeBO3 Cathode Materials for Li-ion Batteries[J]. Chinese Journal of Applied Chemistry, 2011, 28(7): 821-825. doi: 10.3724/SP.J.1095.2011.00522
表面包覆保护的离子电池新型正极材料LiFeBO3电化学性能
English
The Electrochemical Performance of Surface Protected LiFeBO3 Cathode Materials for Li-ion Batteries
Abstract:
The LiFeBO3 cathode materials for Li-ion batteries were prepared by means of solid reaction using lithium metaborate and ferrous oxalate as raw materials.The LiFeBO3 cathode materials were further coated by ethylene propylene copolymer(EPM).The samples were characterized by X-ray diffraction,scanning electron microscopy,and titration analysis.Electrochemical tests of materials showed that LiFeBO3 exhibited a higher discharge mass specific capacity.The electrochemical performance of the coated samples was demonstrated to be improved.Sample coated with 5% EPM had an initial capacity of 190 mA·h/g.It was found that only 4.2% capacity was lost after 50 charge/discharge cyclings at 0.5C.
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Key words:
- lithium ion batteries
- / cathode materials
- / lithium iron borate
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