Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

Citation: XUE Li-Ping, SHAN Li-Li, FENG Wen-Jing. Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology[J]. Chinese Journal of Structural Chemistry, 2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845 shu

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

通讯作者: XUE Li-Ping,

基金项目:
This work was supported by the Natural Science Foundation of China (21401097) for the financial support. (21401097)

摘要: A new cadmium(II) coordination polymer, [Cd(Hcna)₂]_n (1), was hydrothermally synthesized based on 5-(4-carboxyphenoxy)nicotinic acid (H₂cna) organic linker. X-ray single- crystal diffraction determination reveals that 1 crystallizes in the monoclinic P2₁/c space group, with a = 10.101(2), b = 7.9139(17), c = 15.627(3) Å, β = 103.364(3)°, V = 1215.4(4) Å³, Z = 2, M_r = 628.81, D_c= 1.718 Mg/m³, μ = 0.963 mm^-1, F(000) = 628, the final R = 0.0177 and wR = 0.0432 for 2263 observed reflections with I > 2σ(I). In 1, the Cd(II) cations are connected by nicotiniate units to form a two-dimensional (2D) layer, and it is further linked through benzoate units to form a three-dimensional (3D) structure. Topologically, the structure of 1 represents a 3,6-connected 3D rtl topology. Furthermore, thermal stability and photoluminescent property of 1 have also been investigated.

关键词:

English

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: XUE Li-Ping,

Received Date: 15 June 2015
Fund Project:

Abstract: A new cadmium(II) coordination polymer, [Cd(Hcna)₂]_n (1), was hydrothermally synthesized based on 5-(4-carboxyphenoxy)nicotinic acid (H₂cna) organic linker. X-ray single- crystal diffraction determination reveals that 1 crystallizes in the monoclinic P2₁/c space group, with a = 10.101(2), b = 7.9139(17), c = 15.627(3) Å, β = 103.364(3)°, V = 1215.4(4) Å³, Z = 2, M_r = 628.81, D_c= 1.718 Mg/m³, μ = 0.963 mm^-1, F(000) = 628, the final R = 0.0177 and wR = 0.0432 for 2263 observed reflections with I > 2σ(I). In 1, the Cd(II) cations are connected by nicotiniate units to form a two-dimensional (2D) layer, and it is further linked through benzoate units to form a three-dimensional (3D) structure. Topologically, the structure of 1 represents a 3,6-connected 3D rtl topology. Furthermore, thermal stability and photoluminescent property of 1 have also been investigated.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

通讯作者: XUE Li-Ping,

English

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

Corresponding author: XUE Li-Ping,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

通讯作者: XUE Li-Ping,

English

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

Corresponding author: XUE Li-Ping,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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