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A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO2 Adsorption and Luminescent Property

SHENG Dong-Hai ,  DAN Wen-Yan ,  LUO Gen-Xiang ,  DENG Ming-Li

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Citation:  SHENG Dong-Hai, DAN Wen-Yan, LUO Gen-Xiang, DENG Ming-Li. A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO2 Adsorption and Luminescent Property[J]. Chinese Journal of Structural Chemistry, 2016, 35(2): 264-270. doi: 10.14102/j.cnki.0254-5861.2011-0838 shu

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO2 Adsorption and Luminescent Property

  • 1.

    a College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China;

  • 2.

    b Department of Chemistry, Fudan University, Shanghai 200433, China

    • 通讯作者: DENG Ming-Li,
  • 基金项目:

    The project was supported by the NNSFC (No. 21203032) (No. 21203032)

摘要: A three-dimensional coordination polymer, namely {[Zn2(tzba)(dmtrz)(OH)]·3H2O}n (1, H2tzba = 4-(5H-tetrazol)benzoic acid, Hdmtrz = 3,5-dimethyl-1H,1,2,4-triazole), was hydro- thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P21/c space group with a = 8.018(11), b = 21.04(3), c = 11.069(14) Å, β = 91.26(3)°, V = 1867(4) Å3, Z = 4, Dc = 1.729 g/cm3, F(000) = 984, μ = 2.614 mm-1, R(F2 > 2σ(F2)) = 0.0612 and wR(F2) = 0.1533. Topological analysis reveals that compound 1 is a (3,5)-connected structure with a Schläfli symbol of (42.6)(42.65.83), which is a rarely observed lhh topology. In addition, the CO2 adsorption performance and luminescent property of 1 have also been studied.

English

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