Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

Citation: ZHANG Tian, TIAN Ai-Qin, FENG Xun, Seik Weng Ng, TIAN Pan-Hao, WANG Yang. Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid[J]. Chinese Journal of Structural Chemistry, 2016, 35(2): 279-285. doi: 10.14102/j.cnki.0254-5861.2011-0836 shu

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

1.
a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China;
2.
b Basic Courses Education Department, Henan Forestry Vocational College, Luoyang 471002, China;
3.
c Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia;
4.
d Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 80203, Saudi Arabia

通讯作者: FENG Xun,

基金项目:
This work was supported by the National Natural Science Foundation of China (No. 21273101) (No. 21273101)

Technology Project of Henan Province (No. 142102310483) (No. 142102310483)

Key Program of Foundation of Education Committee of Henan Province (No. 14B150033) (No. 14B150033)

摘要: A new cadmium(II) complex [Cd(Hminic)(IP)]_n (1, Hminic = 2-hydroxy-6-methyli- sonicotinic acid, IP = imidazo[4,5-f]-1,10-phenanthroline), has been synthesized by the reaction of a Hminic and auxiliary N-containing ligands with Cd(II) ion under hydrothermal conditions. The complex was studied by elemental analysis, IR spectroscopy and X-ray crystallography. It is formulated as C₂₀H₁₃CdN₅O₃, crystallizes in monoclinic system, space group C2/c with α = 9.6764(8), b = 26.767(2), c = 14.1332(11) Å and b = 97.4510(10)°. V = 3629.7(5) Å³, Z = 8, M_r = 483.75, D_c = 1.770 g/cm³, F(000) = 1484 and µ = 1.237 mm^-1. The final refinement gave R = 0.0309 and wR = 0.0703 for 4151 reflections with I > 2s(I). In the structure of 1, two Cd(II)atoms are joined by a pair of μ₂-hydroxyl oxygen atoms giving rise to a dinuclear Cd(II) unit which is bridged by Hminic linkers to form a 1D ladder-like polymer chain. The chelating ligand IP coordinated to the Cd(II)atom, and alternately attached to both sides of the ladder-like polymer chain. Adjacent chains are further bound together by strong intermolecular hydrogen bonds and face-to-face π…π interactions, resulting in the formation of a 3D supramolecular architecture. Furthermore, the thermal stability and luminescent properties of this complex and the free ligands have been investigated.

关键词:

English

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

1.
a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China;
2.
b Basic Courses Education Department, Henan Forestry Vocational College, Luoyang 471002, China;
3.
c Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia;
4.
d Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 80203, Saudi Arabia

Corresponding author: FENG Xun,

Received Date: 05 June 2015
Fund Project:

Abstract: A new cadmium(II) complex [Cd(Hminic)(IP)]_n (1, Hminic = 2-hydroxy-6-methyli- sonicotinic acid, IP = imidazo[4,5-f]-1,10-phenanthroline), has been synthesized by the reaction of a Hminic and auxiliary N-containing ligands with Cd(II) ion under hydrothermal conditions. The complex was studied by elemental analysis, IR spectroscopy and X-ray crystallography. It is formulated as C₂₀H₁₃CdN₅O₃, crystallizes in monoclinic system, space group C2/c with α = 9.6764(8), b = 26.767(2), c = 14.1332(11) Å and b = 97.4510(10)°. V = 3629.7(5) Å³, Z = 8, M_r = 483.75, D_c = 1.770 g/cm³, F(000) = 1484 and µ = 1.237 mm^-1. The final refinement gave R = 0.0309 and wR = 0.0703 for 4151 reflections with I > 2s(I). In the structure of 1, two Cd(II)atoms are joined by a pair of μ₂-hydroxyl oxygen atoms giving rise to a dinuclear Cd(II) unit which is bridged by Hminic linkers to form a 1D ladder-like polymer chain. The chelating ligand IP coordinated to the Cd(II)atom, and alternately attached to both sides of the ladder-like polymer chain. Adjacent chains are further bound together by strong intermolecular hydrogen bonds and face-to-face π…π interactions, resulting in the formation of a 3D supramolecular architecture. Furthermore, the thermal stability and luminescent properties of this complex and the free ligands have been investigated.

Key words:

1. [1]
  (1) Yaghi, O. M.; O′Keefe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Reticular synthesis and the design of new materials. Nature 2003, 423, 705-714.(1) Yaghi, O. M.; O′Keefe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Reticular synthesis and the design of new materials. Nature 2003, 423, 705-714.
2. [2]
  (2) O′Keeffe, M.; Yaghi, O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 2012, 112, 675-702.(2) O′Keeffe, M.; Yaghi, O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 2012, 112, 675-702.
3. [3]
  (3) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.(3) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.
4. [4]
  (4) Zhao, Y.; Deng, D. S.; Ma, L. F.; Ji, B. M.; Wang, L. Y. A new copper-based metal-organic framework as a promising heterogeneous catalyst for chemo- and regio-selective enamination of b-ketoesters. Chem. Commun. 2013, 49, 10299-10301.(4) Zhao, Y.; Deng, D. S.; Ma, L. F.; Ji, B. M.; Wang, L. Y. A new copper-based metal-organic framework as a promising heterogeneous catalyst for chemo- and regio-selective enamination of b-ketoesters. Chem. Commun. 2013, 49, 10299-10301.
5. [5]
  (5) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2011, 112, 1001-1033.(5) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2011, 112, 1001-1033.
6. [6]
  (6) Pan, M.; Su, C. Y. Coordination assembly of Borromean structures. CrystEngComm. 2014, 16, 7847-7859.(6) Pan, M.; Su, C. Y. Coordination assembly of Borromean structures. CrystEngComm. 2014, 16, 7847-7859.
7. [7]
  (7) Ismayilov, R. H.; Wang, W. Z.; Lee, G. H.; Yeh, C. Y.; Hua, S. A.; Song, Y.; Rohmer, M. M.; Bénard, M.; Peng, S. M. Two linear undecanickel mixed-valence complexes: increasing the size and the scope of the electronic properties of nickel metal strings. Angew. Chem. Int. Ed. 2011, 50, 2045-2048.(7) Ismayilov, R. H.; Wang, W. Z.; Lee, G. H.; Yeh, C. Y.; Hua, S. A.; Song, Y.; Rohmer, M. M.; Bénard, M.; Peng, S. M. Two linear undecanickel mixed-valence complexes: increasing the size and the scope of the electronic properties of nickel metal strings. Angew. Chem. Int. Ed. 2011, 50, 2045-2048.
8. [8]
  (8) Feng, X.; Liu, J.; Guo, J. Z.; Wang, L. Y.; Ng, S. W. A unique manganese (II) 2D polymer containing 2, 5-di(2',4'-dicarboxylphenyl) pyridine and oxalate mixed ligands:Structure and magnetic property, Inorg. Chem. Commun. 2014, 50, 42-47.(8) Feng, X.; Liu, J.; Guo, J. Z.; Wang, L. Y.; Ng, S. W. A unique manganese (II) 2D polymer containing 2, 5-di(2',4'-dicarboxylphenyl) pyridine and oxalate mixed ligands:Structure and magnetic property, Inorg. Chem. Commun. 2014, 50, 42-47.
9. [9]
  (9) Li, C. P.; Du, M. Role of solvents in coordination supramolecular systems. Chem. Commun. 2011, 47, 5958-5972.(9) Li, C. P.; Du, M. Role of solvents in coordination supramolecular systems. Chem. Commun. 2011, 47, 5958-5972.
10. [10]
  (10) Erxleben, A. Structures and properties of Zn(II) coordination polymers. Coord. Chem. Rev. 2003, 246, 203-228.(10) Erxleben, A. Structures and properties of Zn(II) coordination polymers. Coord. Chem. Rev. 2003, 246, 203-228.
11. [11]
  (11) Teo, P.; Hor, T. S. A. Spacer directed metallo-supramolecular assemblies of pyridine carboxylates. Coord. Chem. Rev. 2011, 255, 273-289.(11) Teo, P.; Hor, T. S. A. Spacer directed metallo-supramolecular assemblies of pyridine carboxylates. Coord. Chem. Rev. 2011, 255, 273-289.
12. [12]
  (12) Boča, M.; Jameson, R. F.; Linert, W. Fascinating variability in the chemistry and properties of 2, 6-bis-(benzimidazol-2-yl)-pyridine and 2,6-bis-(benzthiazol-2-yl)-pyridine and their complexes. Coord. Chem. Rev. 2011, 255, 290-317.(12) Boča, M.; Jameson, R. F.; Linert, W. Fascinating variability in the chemistry and properties of 2, 6-bis-(benzimidazol-2-yl)-pyridine and 2,6-bis-(benzthiazol-2-yl)-pyridine and their complexes. Coord. Chem. Rev. 2011, 255, 290-317.
13. [13]
  (13) Mal, D.; Sen, R.; Brandão, P.; Lin, Z. Control formation of rigid linear and flexible zig-zig complexes based on Zn(II) and hydroxyquinoline carboxylate ligand system. Inorg. Chem. Commun. 2013, 30, 111-114.(13) Mal, D.; Sen, R.; Brandão, P.; Lin, Z. Control formation of rigid linear and flexible zig-zig complexes based on Zn(II) and hydroxyquinoline carboxylate ligand system. Inorg. Chem. Commun. 2013, 30, 111-114.
14. [14]
  (14) Yuan, G.; Shao, K. Z.; Hao, X. R.; Pan, Y. R.; Su, Z. M. Synthesis, structure, and photoluminescent property of a trinuclear CdII complex based on semi-rigid bis(imidazole-4,5-dicarboxylate) ligand. Inorg. Chem. Commun. 2014, 42, 15-19.(14) Yuan, G.; Shao, K. Z.; Hao, X. R.; Pan, Y. R.; Su, Z. M. Synthesis, structure, and photoluminescent property of a trinuclear CdII complex based on semi-rigid bis(imidazole-4,5-dicarboxylate) ligand. Inorg. Chem. Commun. 2014, 42, 15-19.
15. [15]
  (15) Sheldrick, G. M. SHELXS97, Program for the Solution of Crystal Structure. University of Göttingen, Germany 1997.(15) Sheldrick, G. M. SHELXS97, Program for the Solution of Crystal Structure. University of Göttingen, Germany 1997.
16. [16]
  (16) Sheldrick, G. M. SHELXL97. Program for the Crystal Structure Refinement. University of Göttingen, Germany 1997.(16) Sheldrick, G. M. SHELXL97. Program for the Crystal Structure Refinement. University of Göttingen, Germany 1997.
17. [17]
  (17) Du, M.; Jiang, X. J.; Zhao, X. J. Molecular tectonics of mixed-ligand metal-organic frameworks (MOFs): positional isomeric effect, metal-directed assembly and structural diversification. Inorg. Chem. 2007, 46, 3984-3995.(17) Du, M.; Jiang, X. J.; Zhao, X. J. Molecular tectonics of mixed-ligand metal-organic frameworks (MOFs): positional isomeric effect, metal-directed assembly and structural diversification. Inorg. Chem. 2007, 46, 3984-3995.
18. [18]
  (18) Desiraju, G. R.; Steiner, T. The Weak Hydrogen Bond in Structural Chemistry and Biology. Oxford University Press: Oxford 1999.(18) Desiraju, G. R.; Steiner, T. The Weak Hydrogen Bond in Structural Chemistry and Biology. Oxford University Press: Oxford 1999.
19. [19]
  (19) Sun, D.; Zhang, N.; Huang, R. B.; Zheng, L. S. Series of Ag(I) coordination complexes derived from aminopyrimidyl ligands and dicarboxylates: syntheses, crystal structures, and properties. Cryst. Growth Des. 2010, 10, 3699-3709.(19) Sun, D.; Zhang, N.; Huang, R. B.; Zheng, L. S. Series of Ag(I) coordination complexes derived from aminopyrimidyl ligands and dicarboxylates: syntheses, crystal structures, and properties. Cryst. Growth Des. 2010, 10, 3699-3709.
20. [20]
  (20) Feng, X.; Feng, Y. Q.; Chen, J. L.; Ng, S. W.; Wang, L. Y. Reticular three-dimensional 3d-4f frameworks constructed through substituted imidazole-dicarboxylate: syntheses, luminescence and magnetic properties study, Dalton Trans. 2015, 44, 804-816.(20) Feng, X.; Feng, Y. Q.; Chen, J. L.; Ng, S. W.; Wang, L. Y. Reticular three-dimensional 3d-4f frameworks constructed through substituted imidazole-dicarboxylate: syntheses, luminescence and magnetic properties study, Dalton Trans. 2015, 44, 804-816.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 2076
HTML全文浏览量: 57

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

通讯作者: FENG Xun,

English

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

Corresponding author: FENG Xun,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

通讯作者: FENG Xun,

English

Synthesis, Crystal Structure and Luminescence Properties of a Cadmium(II) Complex Based on 2-Hydroxy-6-methylisonicotinic Acid

Corresponding author: FENG Xun,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs