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Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

LU Jiu-Fu ,  SHI Juan ,  ZHENG Nan ,  GUO Xiao-Hua ,  GE Hong-Guang

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Citation:  LU Jiu-Fu, SHI Juan, ZHENG Nan, GUO Xiao-Hua, GE Hong-Guang. Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework[J]. Chinese Journal of Structural Chemistry, 2016, 35(2): 319-325. doi: 10.14102/j.cnki.0254-5861.2011-0814 shu

Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

  • 1.

    Chemical Engineering College, Shaanxi University of Technology, Hanzhong 723001, China

  • 基金项目:

    This project was supported by the National Natural Science Foundation of China (No. 21373132)  (No. 21373132)

    the Foundation of Shaanxi university of technology (No. SLGKY15-36) (No. SLGKY15-36)

摘要: A new coordination polymer, {[Ag2(bpp)2(H2O)2]·bpdc·3H2O}n, derived from the ligand biphenyl-4,4'-dicarboxylic acid (H2bpdc), has been obtained through a hydrothermal technique (bpp = 1,3-bis(4-pyridyl)propane). Its single-crystal structure has been characterized by single-crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 consists of 1D infinite [Ag(bpp)(H2O)]nn+ cationic chains, 2D anionic layer constructed by bpdc anions and free water which provide charge compensation in the crystal structure. The 1D infinite [Ag(bpp)(H2O)]nn+ cationic chains and 2D anionic layer are further stacked in -ABAB- fashion through intermolecular H-bonding to form a 3D sandwich-like framework. In addition, the luminescent property of complex 1 in the solid state at room temperature was investigated.

English

  • 
    1. [1]

      (1) Wang, C. C.; Ma, H. W. Crystal structure of catena-bis((1,3-bis(4-pyridyl)propane)-silver(I))benzene-1,4-dicarboxylate octahydrate, [{Ag(C13H14N2)}2][C8H4O4]8H2O. N.C. S. 2007, 222, 101-105.(1) Wang, C. C.; Ma, H. W. Crystal structure of catena-bis((1,3-bis(4-pyridyl)propane)-silver(I))benzene-1,4-dicarboxylate octahydrate, [{Ag(C13H14N2)}2][C8H4O4]8H2O. N.C. S. 2007, 222, 101-105.

    2. [2]

      (2) Lu, J. F.; Min, S. T.; Ge, H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands. J. Chem. Res. 2014, 11, 726-730.(2) Lu, J. F.; Min, S. T.; Ge, H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands. J. Chem. Res. 2014, 11, 726-730.

    3. [3]

      (3) Lu, J. F.; Qiao, L. J.; Li, L. Q.; Liu, Z. H. Syntheses, structures and luminescent properties of four novel Cd/Zn(II) complexes constructed from dicarboxylate and bis(imidazole) co-ligands. J. Mol. Struct. 2015, 1081, 79-84.(3) Lu, J. F.; Qiao, L. J.; Li, L. Q.; Liu, Z. H. Syntheses, structures and luminescent properties of four novel Cd/Zn(II) complexes constructed from dicarboxylate and bis(imidazole) co-ligands. J. Mol. Struct. 2015, 1081, 79-84.

    4. [4]

      (4) Lu, J. F.; Liu, J.; Jiang, M.; Ge, H. G. Synthesis, structure and luminescent property of a 2D Cd(II) coordination polymer based on mixed-ligands of 1,3-bis(imidazol)propane and pyridine-3,5-dicarboxylic acid. Chin. J. Struct. Chem. 2015, 2, 248-252.(4) Lu, J. F.; Liu, J.; Jiang, M.; Ge, H. G. Synthesis, structure and luminescent property of a 2D Cd(II) coordination polymer based on mixed-ligands of 1,3-bis(imidazol)propane and pyridine-3,5-dicarboxylic acid. Chin. J. Struct. Chem. 2015, 2, 248-252.

    5. [5]

      (5) Wang, C. C.; Wang, P. Hydrogen bonding and water networks in a 3-D coordination polymer [Ag(bpp)]2(BDC)·8H2O (bpp = 1,3-bis(4-pyridyl)propane; BDC = benzene-1,4-dicarboxylic acid). Asian J. Chem. 2011, 23, 1449-1452.(5) Wang, C. C.; Wang, P. Hydrogen bonding and water networks in a 3-D coordination polymer [Ag(bpp)]2(BDC)·8H2O (bpp = 1,3-bis(4-pyridyl)propane; BDC = benzene-1,4-dicarboxylic acid). Asian J. Chem. 2011, 23, 1449-1452.

    6. [6]

      (6) Luo, G. G.; Wu, D. L.; Wu, J. H.; Xia, J. X.; Liu, L.; Dai, J. C. Direct observation of conformational change of adipate dianions encapsulated in water clusters. CrystEngComm. 2012, 14, 5377-5380.(6) Luo, G. G.; Wu, D. L.; Wu, J. H.; Xia, J. X.; Liu, L.; Dai, J. C. Direct observation of conformational change of adipate dianions encapsulated in water clusters. CrystEngComm. 2012, 14, 5377-5380.

    7. [7]

      (7) Fu, Z. Y.; Hu, S. M.; Du, W. X.; Zhang, J. J.; Xiang, S. C.; Wu, X. T. Syntheses and structures of two new coordination polymers: [Cu(C14H9O4)(C14H10O4)(C12H12N2)2] and [Ag(C14H9O4)(C13H14N2)]·0.5H2O. Chin. J. Struct. Chem. 2004, 23, 176-182.(7) Fu, Z. Y.; Hu, S. M.; Du, W. X.; Zhang, J. J.; Xiang, S. C.; Wu, X. T. Syntheses and structures of two new coordination polymers: [Cu(C14H9O4)(C14H10O4)(C12H12N2)2] and [Ag(C14H9O4)(C13H14N2)]·0.5H2O. Chin. J. Struct. Chem. 2004, 23, 176-182.

    8. [8]

      (8) Luo, G. G.; Xiong, H. B.; Fu, Z. Y.; Dai, J. C. Observation of the novel ""three-pointed star"" cage-like (H2O)5 cluster in a polymeric solid {[Ag2(bpp)2(H2O)2](chd)·9H2O}n. Sci. Chi. Chem. 2012, 55, 2104-2114.(8) Luo, G. G.; Xiong, H. B.; Fu, Z. Y.; Dai, J. C. Observation of the novel ""three-pointed star"" cage-like (H2O)5 cluster in a polymeric solid {[Ag2(bpp)2(H2O)2](chd)·9H2O}n. Sci. Chi. Chem. 2012, 55, 2104-2114.

    9. [9]

      (9) Luo, G. G.; Xiong, H. B.; Sun, D.; Wu, D. L.; Huang, R. B.; Dai, J. C. A discrete spirocyclic (H2O)9 cluster and 1D novel water chain with tetrameric and octameric clusters in cationic hosts. Cryst. Growth Des. 2011, 11, 1948-1956.(9) Luo, G. G.; Xiong, H. B.; Sun, D.; Wu, D. L.; Huang, R. B.; Dai, J. C. A discrete spirocyclic (H2O)9 cluster and 1D novel water chain with tetrameric and octameric clusters in cationic hosts. Cryst. Growth Des. 2011, 11, 1948-1956.

    10. [10]

      (10) Luo, G. G.; Wu, D. L.; Li, L.; Wu, S. H.; Li, D. X.; Xiao, Z. J.; Dai, J. C. A novel 1D T5(0)A(2) water tape incorporated in the channel of the first 3D silver-suberate framework. J. Mol. Struct. 2012, 1014, 92-96.(10) Luo, G. G.; Wu, D. L.; Li, L.; Wu, S. H.; Li, D. X.; Xiao, Z. J.; Dai, J. C. A novel 1D T5(0)A(2) water tape incorporated in the channel of the first 3D silver-suberate framework. J. Mol. Struct. 2012, 1014, 92-96.

    11. [11]

      (11) Zhao, Q. H.; Chen, J.; Zhu, R. M.; Li, M. Z.; Dai, J. C.; Luo, G. G. Acyclic water tetramer and discrete (H2O)28 cluster with a novel topknot-shaped (H2O)24 cluster coexist in the voids of a Ag(I) polymeric solid. Inorg. Chem. Comm. 2012, 22, 182-186.(11) Zhao, Q. H.; Chen, J.; Zhu, R. M.; Li, M. Z.; Dai, J. C.; Luo, G. G. Acyclic water tetramer and discrete (H2O)28 cluster with a novel topknot-shaped (H2O)24 cluster coexist in the voids of a Ag(I) polymeric solid. Inorg. Chem. Comm. 2012, 22, 182-186.

    12. [12]

      (12) He, W. J.; Luo, G. G.; Wu, D. L.; Liu, L.; Xia, J. X.; Li, D. X.; Dai, J. C.; Xiao, Z. J. An odd-numbered heptameric water cluster containing a puckered pentamer self-assembled in a Ag(I) polymeric solid. Inorg. Chem. Comm. 2012, 18, 4-7.(12) He, W. J.; Luo, G. G.; Wu, D. L.; Liu, L.; Xia, J. X.; Li, D. X.; Dai, J. C.; Xiao, Z. J. An odd-numbered heptameric water cluster containing a puckered pentamer self-assembled in a Ag(I) polymeric solid. Inorg. Chem. Comm. 2012, 18, 4-7.

    13. [13]

      (13) Luo, G. G.; Li, D. X.; Wu, D. L.; Liu, L.; Zhao, Q. H.; Peng, C.; Xiao, Z. J.; Dai, J. C. Characterization of a well-resolved acyclic methanol(water)5 heterohexamer in the solid state. Inorg. Chem. Comm. 2012, 17, 108-112.(13) Luo, G. G.; Li, D. X.; Wu, D. L.; Liu, L.; Zhao, Q. H.; Peng, C.; Xiao, Z. J.; Dai, J. C. Characterization of a well-resolved acyclic methanol(water)5 heterohexamer in the solid state. Inorg. Chem. Comm. 2012, 17, 108-112.

    14. [14]

      (14) Luo, G. G.; Zhu, R. M.; He, W. J.; Li, M. Z.; Zhao, Q. H.; Li, D. X.; Dai, J. C. Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework. J. Mol. Struct. 2012, 1021, 84-88.(14) Luo, G. G.; Zhu, R. M.; He, W. J.; Li, M. Z.; Zhao, Q. H.; Li, D. X.; Dai, J. C. Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework. J. Mol. Struct. 2012, 1021, 84-88.

    15. [15]

      (15) Lu, J. F.; Ge, H. G.; Min, S. T. Syntheses and structural characterization of silver(I) complexes with pyridine and carboxylate derivatives. Rus. J. Coord Chem. 2011, 37, 37-40.(15) Lu, J. F.; Ge, H. G.; Min, S. T. Syntheses and structural characterization of silver(I) complexes with pyridine and carboxylate derivatives. Rus. J. Coord Chem. 2011, 37, 37-40.

    16. [16]

      (16) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area detector Data. University of Göttingen, Germany 1997.(16) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area detector Data. University of Göttingen, Germany 1997.

    17. [17]

      (17) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.(17) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.

    18. [18]

      (18) Sheldrick, G. M. SHELXS-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.(18) Sheldrick, G. M. SHELXS-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.

    19. [19]

      (19) Luo, G. G.; Wu, S. H.; Pan, Z. H.; Xiao, Z. J.; Dai, J. C. Formation of different polymeric water clusters via organic anionic templates: more carboxylate groups used, more water molecules gathered. Inorg. Chem. Comm. 2014, 39, 34-38.(19) Luo, G. G.; Wu, S. H.; Pan, Z. H.; Xiao, Z. J.; Dai, J. C. Formation of different polymeric water clusters via organic anionic templates: more carboxylate groups used, more water molecules gathered. Inorg. Chem. Comm. 2014, 39, 34-38.

    20. [20]

      (20) Huang, X. Y.; Yue, K. F.; Jin, J. C.; Liu, J. Q.; Wang, C. J.; Wang, Y. Y.; Shi, Q. Z. Three-dimensional fivefold interpenetrating microporous metal-organic framework based on mixed flexible ligands. Inorg. Chem. Commun. 2010, 13, 338-341.(20) Huang, X. Y.; Yue, K. F.; Jin, J. C.; Liu, J. Q.; Wang, C. J.; Wang, Y. Y.; Shi, Q. Z. Three-dimensional fivefold interpenetrating microporous metal-organic framework based on mixed flexible ligands. Inorg. Chem. Commun. 2010, 13, 338-341.

    21. [21]

      (21) Kong, Z. G.; Ma, X. Y.; Xu, Z. L.; Wang, X. Y. Synthesis and crystal structure of a new two-dimensional manganese coordination polymer: [Mn(L)(1,4-bdc)]. Chin. J. Struct. Chem. 2011, 30, 927-930.(21) Kong, Z. G.; Ma, X. Y.; Xu, Z. L.; Wang, X. Y. Synthesis and crystal structure of a new two-dimensional manganese coordination polymer: [Mn(L)(1,4-bdc)]. Chin. J. Struct. Chem. 2011, 30, 927-930.

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  • 收稿日期:  2015-05-19
  • 网络出版日期:  2015-07-20
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