Citation:
LIANG Xiao-Qiang, FAN Zeng-Lu. A Metal-organic Framework with Alternately Hydrophilic and Hydrophobic Layers Based on Tetrazole Derivative: Synthesis, Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry,
2015, 34(12): 1901-1907.
doi:
10.14102/j.cnki.0254-5861.2011-0771
A Metal-organic Framework with Alternately Hydrophilic and Hydrophobic Layers Based on Tetrazole Derivative: Synthesis, Structure and Luminescent Property
摘要:
A new metal-organic framework based on ethyl 1H-tetrazole-5-acetate (Hetza), [Ag4(etza)4] (1), has been synthesized and characterized by elemental analysis, IR, thermal gravimetric and X-ray structural analysis. Crystal data for the title complex are as follows: triclinic system, space group P1 with a=11.0771(6), b=11.6636(6), c=13.2925(8), α=102.3710(10), β=103.3810(10), γ=90.0890(10)°, V=1629.60(16) Ǻ3, Mr=1052.06, Z=2, F(000)=1024, Dc=2.144 g/cm3, μ(MoKα)=2.438 mm-1, the final R=0.0538 and wR=0.1475 (I>2σ(I)). Complex 1 adopts the (4·82) topological network and the alternately hydrophilic-hydrophilic and hydrophobic- hydrophobic arrangements. The luminescent properties of complex 1 and the free Hetza ligand have been studied in the solid states.
English
A Metal-organic Framework with Alternately Hydrophilic and Hydrophobic Layers Based on Tetrazole Derivative: Synthesis, Structure and Luminescent Property
Abstract:
A new metal-organic framework based on ethyl 1H-tetrazole-5-acetate (Hetza), [Ag4(etza)4] (1), has been synthesized and characterized by elemental analysis, IR, thermal gravimetric and X-ray structural analysis. Crystal data for the title complex are as follows: triclinic system, space group P1 with a=11.0771(6), b=11.6636(6), c=13.2925(8), α=102.3710(10), β=103.3810(10), γ=90.0890(10)°, V=1629.60(16) Ǻ3, Mr=1052.06, Z=2, F(000)=1024, Dc=2.144 g/cm3, μ(MoKα)=2.438 mm-1, the final R=0.0538 and wR=0.1475 (I>2σ(I)). Complex 1 adopts the (4·82) topological network and the alternately hydrophilic-hydrophilic and hydrophobic- hydrophobic arrangements. The luminescent properties of complex 1 and the free Hetza ligand have been studied in the solid states.
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