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BiVO4基光阳极用于太阳能水分解性能的研究进展

高瑞廷 ,  郭笑天 ,  王蕾

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引用本文: 高瑞廷, 郭笑天, 王蕾. BiVO4基光阳极用于太阳能水分解性能的研究进展[J]. 大学化学, 2026, 41(8): 162-175. doi: 10.12461/PKU.DXHX202507100 shu
Citation:  Rui-Ting Gao,  Xiaotian Guo,  Lei Wang. BiVO4基光阳极用于太阳能水分解性能的研究进展[J]. University Chemistry, 2026, 41(8): 162-175. doi: 10.12461/PKU.DXHX202507100 shu

BiVO4基光阳极用于太阳能水分解性能的研究进展

  • 内蒙古大学化学化工学院, 内蒙古 呼和浩特 010021

    • 通讯作者: 王蕾,E-mial:wanglei@imu.edu.cn
  • 基金项目:

    国家科技重大专项(2022YFA1205200)；国家自然科学基金(22269016,22479083,22405138)；内蒙古自治区“英才兴蒙”工程团队一层次项目(2025TYL03)；内蒙古自治区自然科学基金(2024QN02012)；内蒙古自治区高等学校青年科技英才项目(NJYT25001)

摘要: 光电化学(PEC)水分解是将太阳能转化成氢能的关键技术之一。在众多半导体光阳极材料中，BiVO4因其适中的带隙(2.4-2.5 eV)、良好的化学稳定性、环境友好以及易于合成等优点，被视为是一种极具潜力的候选材料。然而，其PEC效率受到载流子迁移速率以及严重的体相与表面复合的限制。近期研究表明，通过针对性的改性策略可以有效克服这些瓶颈，显著提升BiVO4的光电化学性能。本文系统综述了关键的优化策略，包括纳米结构调控、掺杂(本征/外源)、异质结构筑、表面钝化以及助催化剂负载，并分析了这些策略对电荷分离与传输动力学的影响。最后，对BiVO4基光电化学系统未来的研究方向进行了展望。

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  • 发布日期:  2025-12-16
  • 收稿日期:  2025-07-21
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