含肟基Schiff碱配体及其Cu(Ⅱ)配合物的合成及超分子结构

孙银霞 陆瑞娥 李新然 赵亚元 李春宇

引用本文: 孙银霞, 陆瑞娥, 李新然, 赵亚元, 李春宇. 含肟基Schiff碱配体及其Cu(Ⅱ)配合物的合成及超分子结构[J]. 无机化学学报, 2015, (5): 1055-1062. doi: 10.11862/CJIC.2015.134 shu
Citation:  SUN Yin-Xia, LU Rui-E, LI Xin-Ran, ZHAO Ya-Yuan, LI Chun-Yu. A Schiff Base Ligand Containing Oxime Group and its Cu(Ⅱ) Complex: Syntheses and Supramolecular Structures[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 1055-1062. doi: 10.11862/CJIC.2015.134 shu

含肟基Schiff碱配体及其Cu(Ⅱ)配合物的合成及超分子结构

    通讯作者: 孙银霞 sun_yinxia@163.com
  • 基金项目:

    兰州交通大学青年科学基金(No.2011007) (No.2011007)

    兰州交通大学研究生教改项目(No.160012)资助。 (No.160012)

摘要: 合成了一个含肟基Schiff碱配体(HL,C15H16N2O)及其Cu(Ⅱ)配合物[CuL2],采用元素分析、红外光谱、紫外光谱以及X-射线单晶衍射分析进行了表征。结果表明,配体HL结构中,一对HL分子通过分子间的Cl…Cl卤键(Cl…Cl的距离为0.3459(3)nm)链接形成了二聚体,每个二聚体通过分子间C-H…π作用链接其它4个相邻的二聚体形成了无限的三维超分子网状结构。Cu(Ⅱ)配合物为单核结构,由1个Cu(Ⅱ)离子和2个双齿配体组成。Cu(Ⅱ)离子的配位数为4,具有平面四边形结构。在Cu(Ⅱ)配合物结构中每个配合物分子通过分子间C-H…π作用链接其它4个相邻的分子形成了二维层状超分子结构,这种层状结构通过ππ堆积作用而进一步连接。

English

  • 
    1. [1] Kim J, Chen B, Reineke T M, et al. J. Am. Chem. Soc., 2001,123(34):8239-8247[1] Kim J, Chen B, Reineke T M, et al. J. Am. Chem. Soc., 2001,123(34):8239-8247

    2. [2] Lacroix P G. Eur. J. Inorg. Chem., 2001(2):339-348[2] Lacroix P G. Eur. J. Inorg. Chem., 2001(2):339-348

    3. [3] Sharma A K, Lloret F, Mukherjee R N. Inorg. Chem., 2007, 46(13):5128-5130[3] Sharma A K, Lloret F, Mukherjee R N. Inorg. Chem., 2007, 46(13):5128-5130

    4. [4] Percy G C, Thornton J. J. Inorg. Nucl. Chem., 1973,35:2319-2327[4] Percy G C, Thornton J. J. Inorg. Nucl. Chem., 1973,35:2319-2327

    5. [5] Adhikary C, Sen R, Bocelli G, et al. J. Coord. Chem., 2009, 62(22):3573-3582[5] Adhikary C, Sen R, Bocelli G, et al. J. Coord. Chem., 2009, 62(22):3573-3582

    6. [6] Rajasekar M, Sreedaran S, Prabu R. et al. J. Coord. Chem., 2010,63:136-146[6] Rajasekar M, Sreedaran S, Prabu R. et al. J. Coord. Chem., 2010,63:136-146

    7. [7] Dong W K, Sun, Y X, Zhang Y P, et al. Inorg. Chim. Acta, 2009,362(1):117-124[7] Dong W K, Sun, Y X, Zhang Y P, et al. Inorg. Chim. Acta, 2009,362(1):117-124

    8. [8] Dong W K, He X N, Yan H B, et al. Polyhedron, 2009,28 (8):1419-1428[8] Dong W K, He X N, Yan H B, et al. Polyhedron, 2009,28 (8):1419-1428

    9. [9] Dong W K, Zhao C Y, Sun Y X, et al. Inorg. Chem. Comm., 2009,12(3):234-236[9] Dong W K, Zhao C Y, Sun Y X, et al. Inorg. Chem. Comm., 2009,12(3):234-236

    10. [10] Dong W K, Duan J G, Guan Y H, et al. Inorg. Chim. Acta, 2009,362(4):1129-1134[10] Dong W K, Duan J G, Guan Y H, et al. Inorg. Chim. Acta, 2009,362(4):1129-1134

    11. [11] Katsuki T. Coord. Chem. Rev., 1995,140:189-214[11] Katsuki T. Coord. Chem. Rev., 1995,140:189-214

    12. [12] Summers M F, Marzilli L G, Bresciani-Pahor N, et al. J. Am. Chem. Soc., 1984,106:4478-4485[12] Summers M F, Marzilli L G, Bresciani-Pahor N, et al. J. Am. Chem. Soc., 1984,106:4478-4485

    13. [13] Lacroix P G. Eur. J. Inorg. Chem., 2001(2):339-348[13] Lacroix P G. Eur. J. Inorg. Chem., 2001(2):339-348

    14. [14] Sun S S, Stern C L, Nguyen S T, et al. J. Am. Chem. Soc., 2004,126:6314-6326[14] Sun S S, Stern C L, Nguyen S T, et al. J. Am. Chem. Soc., 2004,126:6314-6326

    15. [15] Koehler K, Sandstrom W, Cordes E H. J. Am. Chem. Soc., 1964,86(13):2413-2419[15] Koehler K, Sandstrom W, Cordes E H. J. Am. Chem. Soc., 1964,86(13):2413-2419

    16. [16] DONG Wen-Kui(董文魁), TANG Xiao-Lu(唐晓璐), HE Xue-Ni(何雪妮), et al. Chinese. J. Inorg. Chem.(无机化学学 报), 2009,25(3):528-532[16] DONG Wen-Kui(董文魁), TANG Xiao-Lu(唐晓璐), HE Xue-Ni(何雪妮), et al. Chinese. J. Inorg. Chem.(无机化学学 报), 2009,25(3):528-532

    17. [17] Sheldrick G M. SHELXS 97, Program for Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[17] Sheldrick G M. SHELXS 97, Program for Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    18. [18] Wu H L, Yuan J K, Bai Y, et al. Transition Met. Chem., 2011,36:819-827[18] Wu H L, Yuan J K, Bai Y, et al. Transition Met. Chem., 2011,36:819-827

    19. [19] Wu H L, Li K, Sun T, et al. Transition Met. Chem., 2011, 36:21-28[19] Wu H L, Li K, Sun T, et al. Transition Met. Chem., 2011, 36:21-28

    20. [20] Ghosh T, Mondal B, Ghosh T, et al. Inorg. Chim. Acta, 2007,360:1753-1761[20] Ghosh T, Mondal B, Ghosh T, et al. Inorg. Chim. Acta, 2007,360:1753-1761

    21. [21] Smith H E. Chem. Rev., 1983,83:359-377[21] Smith H E. Chem. Rev., 1983,83:359-377

    22. [22] Dong W K, Sun Y X, Liu G H, et al. Z. Anorg. Allg. Chem., 2012,638(9):1370-1377[22] Dong W K, Sun Y X, Liu G H, et al. Z. Anorg. Allg. Chem., 2012,638(9):1370-1377

    23. [23] Akine S, Taniguchi T, Nabeshima T. Chem. Lett., 2001,30: 682-683[23] Akine S, Taniguchi T, Nabeshima T. Chem. Lett., 2001,30: 682-683

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  1388
  • HTML全文浏览量:  340
文章相关
  • 收稿日期:  2015-01-03
  • 网络出版日期:  2015-03-28
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章