基于前驱体Pb(OH)I溶液法制备FAPbI<sub>3</sub>太阳能电池

引用本文: 朱慧敏, 王栋, 于勇, 段咏欣, 逄淑平, 崔光磊. 基于前驱体Pb(OH)I溶液法制备FAPbI₃太阳能电池[J]. 无机化学学报, 2015, (5): 1003-1009. doi: 10.11862/CJIC.2015.126 shu

Citation: ZHU Hui-Min, WANG Dong, YU Yong, DUAN Yong-Xin, PANG Shu-Ping, CUI Guang-Lei. Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 1003-1009. doi: 10.11862/CJIC.2015.126 shu

基于前驱体Pb(OH)I溶液法制备FAPbI₃太阳能电池

朱慧敏 ^1, ,
王栋 ^2, ,
于勇 ^1, ,
段咏欣 ^1, ,
逄淑平 ^{2,
,} ,
崔光磊 ^2,

1.
1 青岛科技大学高分子学院橡塑材料与工程教育部重点实验室, 青岛 266042;
2.
2 中国科学院青岛生物能源与过程研究所, 青岛 266101

通讯作者: 逄淑平 pangsp@qibebt.ac.cn

基金项目:
国家自然科学基金(No.51202266) (No.51202266)

青岛研究项目(No.13-1-4-228-jch)资助。 (No.13-1-4-228-jch)

摘要: 甲脒铅碘因具有高热稳定性和较窄的禁带宽度而受到广泛关注。本工作使用羟基碘化铅代替传统碘化铅、氯化铅,通过一步溶液法制备介孔甲脒铅碘钙钛矿太阳能电池,研究退火温度对材料的结晶性、覆盖层形貌和器件的效率等方面的影响。较之传统的溶液法工艺,基于羟基碘化铅制备的甲脒铅碘薄膜表现出更为优异的热稳定性能。最终在AM 1.5G一个太阳光照明下,得到了5.8%的光电转化效率,其中短路电流为18.6mA·cm^-2,开路电压为0.67V,填充因子为0.47。

关键词:

Pb(OH)I;FAPbI₃;钙钛矿;一步旋涂工艺

English

Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor

1.
1 Key Laboratory of Rubber and Plastics Ministry of Education, Institute of polymer, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;
2.
2 Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technology, Qingdao Institute of Bioprocess Technology, Chinese Academy of Sciences, Qingdao, Shandong 266101, China

Corresponding author: 逄淑平 pangsp@qibebt.ac.cn

Received Date: 13 November 2014
Fund Project:
国家自然科学基金(No.51202266)

青岛研究项目(No.13-1-4-228-jch)资助。

Abstract: Formamidine lead iodine becomes extremely promising for its highly thermal stability and narrow band gap. In this work, we have employed a hydroxyl iodine lead precursor to replace lead chloride and lead iodide to fabricate a pure phase formamidine lead iodine perovskite in mesoscopic solar cells based on the one-step solution processing method and then studied the effect of annealing temperature on the material crystallinity, the morphology of capping layer and devices efficiency etc. Compared with the traditional solution processing methods, the hydroxyl iodine lead derived formamidine lead iodine film delivers an improved textured structure and thermal stability. As a result, a short circuit photocurrent density of 18.6 mA·cm^-2, an open circuit voltage of 0.67 mV, fill factor of 0.47, and a power conversion efficiency of 5.8% are achieved under the simulated AM 1.5G one sun illumination.

Key words:

Pb(OH)I;FAPbI₃;perovskite;one-step spin-coating

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于前驱体Pb(OH)I溶液法制备FAPbI₃太阳能电池

通讯作者: 逄淑平 pangsp@qibebt.ac.cn

English

Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor

Corresponding author: 逄淑平 pangsp@qibebt.ac.cn

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通讯作者: 陈斌, bchen63@163.com

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基于前驱体Pb(OH)I溶液法制备FAPbI3太阳能电池

通讯作者: 逄淑平 pangsp@qibebt.ac.cn

English

Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor

Corresponding author: 逄淑平 pangsp@qibebt.ac.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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