基于刚性四面体含硅配体构筑的两个钴配位聚合物及其结构多样性

引用本文: 薛云珊, 许岩, 杜红宾. 基于刚性四面体含硅配体构筑的两个钴配位聚合物及其结构多样性[J]. 无机化学学报, 2015, (5): 981-988. doi: 10.11862/CJIC.2015.125 shu

Citation: XUE Yun-Shan, XU Yan, DU Hong-Bin. Structural Diversity of Coordination Polymers Built from a Rigid Silicon-Based Tetracarboxylate Linker[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 981-988. doi: 10.11862/CJIC.2015.125 shu

基于刚性四面体含硅配体构筑的两个钴配位聚合物及其结构多样性

薛云珊 ^1,2, ,
许岩 ^3, ,
杜红宾 ^{1,
,}

1.
1 南京大学化学化工学院, 配位化学国家重点实验室, 南京 210093;
2.
2 盐城师范学院化学化工学院, 盐城 224051;
3.
3 南京工业大学化学化工学院, 材料化学工程国家重点实验室, 南京 210009

通讯作者: 杜红宾 nic7501@scu.edu.cn

基金项目:
国家自然科学基金(No.21173153) (No.21173153)

四川省科技厅科技支撑项目(2011GZ0035)资助。 (2011GZ0035)

摘要: 基于四齿刚性羧酸配体H₄L(H₄L=4,4',4",4"'-silanetetrayltetrabenzoic acid)在水热条件下合成了2个微孔配位聚合物,分别是[CoL][NH₂(CH₃)₂]₂·2.25H₂O(1)和[Co₃L₂]H₃O]₂·4DMA(2)(DMA=N,N-二甲基乙酰胺)。晶体结构分析表明这2个化合物均属于正交晶系,晶体1的空间群是Pbca,晶胞参数是a=2.2702(2)nm,b=1.4565(7)nm,c=2.8264(7)nm,晶体2的空间群是Pnna,晶胞参数是a=2.6982(3)nm,b=2.1882(2)nm,c=1.3821(9)nm。化合物1是由四面体型的单核钴和4-连接的配体构成的sra拓扑的三维结构。化合物2是由三核钴{Co₃(COO)₈}和4-连接的四面体型配体构成的、带有一维孔道的双节点(4,8)-连接的alb三维网络结构。讨论了由H₄L构成的配位聚合物的结构多样性。

关键词:

配位聚合物;晶体结构;钴;配体

English

Structural Diversity of Coordination Polymers Built from a Rigid Silicon-Based Tetracarboxylate Linker

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224051, China;
3.
3 College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

Corresponding author: 杜红宾 nic7501@scu.edu.cn

Received Date: 08 November 2014
Fund Project:
国家自然科学基金(No.21173153)

四川省科技厅科技支撑项目(2011GZ0035)资助。

Abstract: By using a rigid tetrapodal carboxylate linker 4,4',4",4"'-silanetetrayltetrabenzoic acid (H₄L), two open-framework coordination polymers, namely, [CoL][NH₂(CH₃)₂]2·2.25H₂O (1) and [Co₃L₂]H₃O]₂·4DMA (2) (DMA=N, N-Dimethylacetamide), were solvothermally synthesized and structurally characterized. The crystal structure analyses indicate that both compounds crystallize in orthorhombic system. The unit cell parameters for compound 1 are space group Pbca, a=2.2702(2) nm, b=1.4565(7) nm, c=2.8264(7) nm, and for compound 2, space group Pnna, a=2.6982(3) nm, b=2.1882(2) nm, c=1.3821(9) nm. Compound 1 is a 3D framework built on tetrahedral Co units and a 4-connecting ligand Lto give a 4-connected sra structure. Compound 2 is a 3D 2-nodal (4,8)-connected alb network with small 1D channels built from a trinuclear {Co₃(COO)₈} unit and a 4-connected tetrahedral Lligand. The structure diversity of H₄L-based MOFs is discussed.

Key words:

coordination polymer;crystal structure;cobalt;ligand

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于刚性四面体含硅配体构筑的两个钴配位聚合物及其结构多样性

通讯作者: 杜红宾 nic7501@scu.edu.cn

English

Structural Diversity of Coordination Polymers Built from a Rigid Silicon-Based Tetracarboxylate Linker

Corresponding author: 杜红宾 nic7501@scu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于刚性四面体含硅配体构筑的两个钴配位聚合物及其结构多样性

通讯作者: 杜红宾 nic7501@scu.edu.cn

English

Structural Diversity of Coordination Polymers Built from a Rigid Silicon-Based Tetracarboxylate Linker

Corresponding author: 杜红宾 nic7501@scu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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