Ag2O-Bi2MoO6:制备及光催化降解富里酸

引用本文: 张月, 赵雪姣, 段元首, 苏秀荣. Ag₂O-Bi₂MoO₆:制备及光催化降解富里酸[J]. 无机化学学报, 2015, (5): 939-946. doi: 10.11862/CJIC.2015.108 shu

Citation: ZHANG Yue, ZHAO Xue-Jiao, DUAN Yuan-Shou, SU Xiu-Rong. Ag₂O Doped Bi₂MoO₆: Preparation and Photocatalytic Activity for Fulvic Acid Degradation[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 939-946. doi: 10.11862/CJIC.2015.108 shu

Ag₂O-Bi₂MoO₆:制备及光催化降解富里酸

1.
山东农业大学化学与材料科学学院, 泰安 271018

通讯作者: 苏秀荣 zfyancat@upc.edu.cn

基金项目:
国家自然科学基金(No.U1362202) (No.U1362202)

山东省自然科学基金(No.ZR2011BQ014) (No.ZR2011BQ014)

中央高校基本科研业务费专项资金(No.12CX04093A)资助项目。 (No.12CX04093A)

摘要: 以钼酸铵、硝酸铋和硝酸银为原料,以十六烷基三甲基溴化铵(CTAB)为辅助活性剂,采用水热法合成了Ag₂O-Bi₂MoO₆光催化剂。用X射线粉末衍射、扫描电镜及紫外-可见吸收光谱等进行表征,并对水中天然有机物富里酸进行了光催化氧化研究。结果表明:未掺杂钼酸铋表面平滑,Ag₂O-Bi₂MoO₆表面有明显的小块颗粒存在,分布集中,且其XRD图出现Ag₂O的衍射峰。与未掺杂样品相比,掺杂Ag₂O后Bi₂MoO₆的可见光催化活性提高,当掺银量为1.5%时活性最高。实验最佳催化剂浓度为0.6g·L^-1,在溶液pH值减小、富里酸初始浓度减小时有助于富里酸的去除。富里酸降解过程符合一级反应动力学方程,拟合方程为y=-0.0195x。对富里酸降解产物进行发光菌生物毒性测试,发现光催化2h后降解产物比处理前毒性降低约90%。

关键词:

钼酸铋;富里酸;掺杂;光催化氧化;动力学;毒性测试

English

Ag₂O Doped Bi₂MoO₆: Preparation and Photocatalytic Activity for Fulvic Acid Degradation

1.
College of Chemistry and Material Science, Shandong Agricultural University, Tai'an, Shandong 271018, China

Corresponding author: 苏秀荣 zfyancat@upc.edu.cn

Received Date: 05 December 2014
Fund Project:
国家自然科学基金(No.U1362202)

山东省自然科学基金(No.ZR2011BQ014)

中央高校基本科研业务费专项资金(No.12CX04093A)资助项目。

Abstract: We use ammonium molybdate, bismuth nitrate and silver nitrate as raw materials, hexadecyl trimethyl ammonium bromide(CTAB) as auxiliary surfactant to synthesize photocatalyst Ag₂O-Bi₂MoO₆ via hydrothermal method. The photocatalyst was characterized by XRD, SEM and UV-Vis spectroscopy. The photocatalytic oxidation of fulvic acid in water was performed over the catalyst. The results show that the surface of pure bismuth molybdate is smooth while on the surface of Ag₂O-Bi₂MoO₆ there are some well-distributed small grains. The XRD pattern of Ag₂O-Bi₂MoO₆ shows diffraction peaks of Ag₂O. Compared with the pure sample, Ag₂O-Bi₂MoO₆ has much higher photocatalytic activity under visible light, and when its doping level is 1.5%, it shows the highest activity. The best catalyst concentration is 0.6 g·L^-1. The decrease in pH value of the solvent and initial concentration of fulvic acid will promote the removal of fulvic acid. The degradation process of fulvic acid conforms the first order kinetics, and the fitting equation is y=-0.0195x. A Photobacterium phosphoreum toxicity test results show that the toxicity of the 2 h photocatalytic degradation product is reduced by about 90% compared to the un-degraded fulvic acid.

Key words:

bismuth molybdate;fulvic acid;doping;photocatalytic oxidation;kinetic;toxicity test

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ag₂O-Bi₂MoO₆:制备及光催化降解富里酸

通讯作者: 苏秀荣 zfyancat@upc.edu.cn

English

Ag₂O Doped Bi₂MoO₆: Preparation and Photocatalytic Activity for Fulvic Acid Degradation

Corresponding author: 苏秀荣 zfyancat@upc.edu.cn

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