3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构

引用本文: 储兆晶, 白晓光, 王玉成, 陈金梅, 赵红. 3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构[J]. 无机化学学报, 2014, 30(4): 945-951. doi: 10.11862/CJIC.2014.148 shu

Citation: CHU Zhao-Jing, BAI Xiao-Guang, WANG Yu-Cheng, CHEN Jin-Mei, ZHAO Hong. Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 945-951. doi: 10.11862/CJIC.2014.148 shu

3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构

储兆晶 ^1, ,
白晓光 ^2, ,
王玉成 ^2, ,
陈金梅 ^1, ,
赵红 ^{1,
,}

通讯作者: 赵红 zhaohong@seu.edu.cn

基金项目:
国家自然科学基金(No.20801012) (No.20801012)

江苏爱纳吉新能源科技有限公司(No.8507040091)资助项目。 (No.8507040091)

摘要: 以3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑(Athpp)为配体合成了2个金属配合物即CoCl₄(Athpp)₂·2H₂O(1)和CuCl₄(Athpp)₂(2)。用红外、元素分析和X-射线单晶衍射等手段表征了晶体结构。配合物1结晶在P1空间群而配合物2结晶在P2₁/n空间群。金属中心均采取扭曲八面体构型。此外,还研究了配合物的固体荧光性质

关键词:

钴(Ⅱ)配合物;铜(Ⅱ)配合物;晶体结构;吡唑衍生物

English

Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

1.
1 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China;

Corresponding author: 赵红 zhaohong@seu.edu.cn

Received Date: 08 October 2013
Fund Project:
国家自然科学基金(No.20801012)

江苏爱纳吉新能源科技有限公司(No.8507040091)资助项目。

Abstract: Two compounds CoCl₄(Athpp)₂·2H₂O (1) and CuCl₄(Athpp)₂ (2) were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole (Athpp) with cobalt(Ⅱ) chlorine and copper(Ⅱ) chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P2₁/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature.

Key words:

cobalt(Ⅱ) compound;copper(Ⅱ) compound;crystal structure;pyrazole derivative

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沈阳化工大学材料科学与工程学院沈阳 110142

3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构

通讯作者: 赵红 zhaohong@seu.edu.cn

English

Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

Corresponding author: 赵红 zhaohong@seu.edu.cn

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中国化学会秘书处

3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构

通讯作者: 赵红 zhaohong@seu.edu.cn

English

Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

Corresponding author: 赵红 zhaohong@seu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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