4-氯苯乙酸构筑的一维铅配位聚合物的晶体结构、荧光性质和生物活性

薛俭雷 ,  田春华

引用本文: 薛俭雷, 田春华. 4-氯苯乙酸构筑的一维铅配位聚合物的晶体结构、荧光性质和生物活性[J]. 无机化学学报, 2014, 30(4): 907-912. doi: 10.11862/CJIC.2014.140 shu
Citation:  XUE Jian-Lei, TIAN Chun-Hua. Lead(Ⅱ) Coordination Polymer with 4-Chlorophenoxyacetate as Ligand:Structure, Luminescence and Biological Bctivity[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 907-912. doi: 10.11862/CJIC.2014.140 shu

4-氯苯乙酸构筑的一维铅配位聚合物的晶体结构、荧光性质和生物活性

    通讯作者: 田春华 tianchunhua1980@163.com
  • 基金项目:

    黑龙江省教育厅科学技术研究基金(No.12521640,12531833)资助项目。 (No.12521640,12531833)

摘要: 水热条件下采用Pb(NO3)2和4-氯苯乙酸作为反应物合成出1个新的一维铅配位聚合物[Pb(4-cpa)2(H2O)]n(1)(4-Hcpa=4-氯苯乙酸),并分别用元素分析、红外光谱、差热分析、X-射线粉末衍射和X-射线单晶衍射等表征了该结构。晶体结构分析结果表明:μ3桥联的4-氯苯甲酸将铅金属离子连接成一维链结构。荧光分析表明常温固态下配合物11发射蓝色荧光,且在422nm处的荧光寿命为5.3ns。以除草剂-精喹禾灵为对照品,考察了配体4-Hcpa和配合物1的生物活性。

English

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  • 收稿日期:  2013-07-11
  • 网络出版日期:  2013-11-21
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