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3,5-二氨基苯甲酸构筑的Zn(Ⅱ)、Cd(Ⅱ)两种配合物的合成及晶体结构

张美丽 ,  任宜霞 ,  陈小利 ,  闫洪涛

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引用本文: 张美丽, 任宜霞, 陈小利, 闫洪涛. 3,5-二氨基苯甲酸构筑的Zn(Ⅱ)、Cd(Ⅱ)两种配合物的合成及晶体结构[J]. 无机化学学报, 2014, 30(4): 895-900. doi: 10.11862/CJIC.2014.132 shu
Citation:  ZHANG Mei-Li, REN Yi-Xia, CHEN Xiao-Li, YAN Hong-Tao. Synthesis and Crystal Structure of Zn(Ⅱ)、Cd(Ⅱ) Two Complexes Constructed from 3,5-Diaminobenzoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 895-900. doi: 10.11862/CJIC.2014.132 shu

3,5-二氨基苯甲酸构筑的Zn(Ⅱ)、Cd(Ⅱ)两种配合物的合成及晶体结构

    通讯作者: 张美丽 ydzml2332041@163.com
  • 基金项目:

    陕西省教育厅科研基金(No.11JK0567,11JK0565,12JK0636) (No.11JK0567,11JK0565,12JK0636)

    延安大学自然基金(No.YDZD2011-07)资助项目。 (No.YDZD2011-07)

摘要: 利用3,5-二氨基苯甲酸配体合成了2种新的配合物[Cd(diaba)(phen)2]NO3·H2O(1)和[Zn(diaba)(2,2’-bipy)2](2)(H2diaba=3,5-diaminobenzoicacid；phen=1,10-phenanthroline,2,2’-bipy=2,2’-bipyridine),并对其进行了元素分析、红外光谱和X射线单晶衍射测定。配合物1属于正交晶系,空间群为Fddd,a=1.42581(7)nm,b=2.56462(13)nm,c=3.09247(17)nm。配合物2属于单斜晶系,空间群为C2/c,a=1.27362nm,b=1.59278nm,c=1.51935nm,β=107.334°。配合物1和2都为单核晶体。配合物1的结构单元由1个CdⅡ、1个3,5-二氨基苯甲酸和2个phen构成。配合物2的结构单元由1个ZnⅡ、1个3,5-二氨基苯甲酸和2个2,2’-bipy构成。两种配合物再通过氢键或π-π堆积形成三维超分子网络。研究了配合物的热稳定性和荧光性质。

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  • 收稿日期:  2013-05-02
  • 网络出版日期:  2013-11-13
通讯作者: 陈斌, bchen63@163.com
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