氢氧化物盐插层材料的制备和表征

引用本文: 刘洁翔, 张永清, 张晓光, 王建龙, 赵凌峰, 杨津, 王瑞. 氢氧化物盐插层材料的制备和表征[J]. 无机化学学报, 2014, 30(4): 837-844. doi: 10.11862/CJIC.2014.129 shu

Citation: LIU Jie-Xiang, ZHANG Yong-Qing, ZHANG Xiao-Guang, WANG Jian-Long, ZHAO Ling-Feng, YANG Jin, WANG Rui. Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 837-844. doi: 10.11862/CJIC.2014.129 shu

氢氧化物盐插层材料的制备和表征

刘洁翔 ^{1,
,} ,
张永清 ^1, ,
张晓光 ^{2,
,} ,
王建龙 ^1, ,
赵凌峰 ^1, ,
杨津 ^1, ,
王瑞 ^1,

通讯作者: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

基金项目:
河北省自然科学基金(No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050) (No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050)

“大学生创新创业训练计划”国家级项目(No.201310080018)资助项目。 (No.201310080018)

摘要: 以层状氢氧化锌硝酸盐(Zn-LHS)和氢氧化镍锌硝酸盐(NiZn-LHS)为主体,采用共沉淀和离子交换法制备十二烷基苯磺酸根离子(DBS)和磺丁基醚-β-环糊精(SBE-β-CD)插层氢氧化物盐(Zn-LHS-DBS和NiZn-LHS-SBE-β-CD),系统考察客体阴离子浓度和pH值等因素对插层材料超分子结构的影响,并用XRD、FT-IR、TG-DTA和SEM对其结构、热稳定性和形貌等进行表征。结果表明,采用共沉淀法在DBS浓度为0.19~0.38mol·L^-1,pH=6.0~7.0,水热温度60~100℃条件下合成晶型单一且结构完整Zn-LHS-DBS；采用离子交换法可合成结构完整NiZn-LHS-SBE-β-CD；无论离子交换还是共沉淀法都不能合成单一晶型Zn-LHS-SBE-β-CD,这可能与SBE-β-CD分子结构以及Zn-LHS水热稳定性差有关。此外,由于氢氧化物盐层板和客体间存在超分子作用而导致DBS和SBE-β-CD在层间具有较高热稳定性。

关键词:

氢氧化锌硝酸盐;氢氧化镍锌硝酸盐;十二烷基苯磺酸钠;磺丁基醚-β-环糊精;热稳定性

English

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;

Corresponding author: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

Received Date: 15 September 2013
Fund Project:
河北省自然科学基金(No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050)

“大学生创新创业训练计划”国家级项目(No.201310080018)资助项目。

Abstract: Intercalation of dodecyl benzene sulphonate (DBS) and sulfobutyl ether β-cyclodextrin (SBE-β-CD) into layered zinc hydroxide nitrate (Zn-LHS) and nickel/zinc hydroxide nitrate (NiZn-LHS) was synthesized by coprecipitation and ion-exchanged methods. The effect of anion concentration and pHvalue on preparation was systematically investigated and compared. The products were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetry and differential thermal analysis (TG-DTA), and scanning electron microscope (SEM). The results showed that Zn-LHS-DBS with pure phase and good crystallinity was obtained at DBS concentration of 0.19~0.38 mol·L^-1, pH=6.0~7.0, temperature of hydrothermal treatment of 60~100 ℃ by coprecipitation method. The NiZn-LHS-SBE-β-CD with good structure was prepared by ion-exchanged method. Zn-LHS-SBE-β-CD with pure phase was not successfully prepared by both coprecipitation and ion-exchanged method due to the particular structure of SBE-β-CD and poor hydrothermal stability of Zn-LHS. Furthermore, TG-DTA data indicated that stability of SBE-β-CD and DBSimproved distinctly in the interlayer due to the strong supra-molecular interaction existed between anions and hostlayer of LHS.

Key words:

zinc hydroxide nitrate;nickel/zinc hydroxide nitrate;dodecyl benzene sulphonate;sulfobutyl ether β-cyclodextrin;thermostability

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沈阳化工大学材料科学与工程学院沈阳 110142

氢氧化物盐插层材料的制备和表征

通讯作者: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

English

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

Corresponding author: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

氢氧化物盐插层材料的制备和表征

通讯作者: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

English

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

Corresponding author: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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