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基于对叔丁基杯[8]芳烃的3d-5f核簇化合物(MxThy, M=Co、Ni、Zn)的合成、结构与磁性研究

杜尚超 ,  谭华桥 ,  毕研峰 ,  于洋 ,  廖伍平

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引用本文: 杜尚超, 谭华桥, 毕研峰, 于洋, 廖伍平. 基于对叔丁基杯[8]芳烃的3d-5f核簇化合物(MxThy, M=Co、Ni、Zn)的合成、结构与磁性研究[J]. 无机化学学报, 2014, 30(4): 749-756. doi: 10.11862/CJIC.2014.112 shu
Citation:  DU Shang-Chao, TAN Hua-Qiao, BI Yan-Feng, YU Yang, LIAO Wu-Ping. Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene：Syntheses, Structures and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 749-756. doi: 10.11862/CJIC.2014.112 shu

基于对叔丁基杯[8]芳烃的3d-5f核簇化合物(MxThy, M=Co、Ni、Zn)的合成、结构与磁性研究

    通讯作者: 廖伍平 wpliao@ciac.jl.cn
  • 基金项目:

    国家自然科学基金(21221061,51222404,51074148,91026024) (21221061,51222404,51074148,91026024)

    973项目(2012CBA01206)资助项目。 (2012CBA01206)

摘要: 本文以对叔丁基杯[8]芳烃(H8C8A)为配体,在溶剂热条件下制得了3个3d-5f化合物,[Co2Th4(HC8A)2O2(OH)2(DMF)6](1)、[Ni2Th5(H2C8A)(C8A)O4(OH)2(DMF)5(CH3OH)2](2)、[Zn2Th6(HC8A)(C8A)O5(CH3O)(C3H6NO2)2(DMF)5(CH3OH)](3)(其中H8C8A=对叔丁基杯[8]芳烃,DMF=N,N-二甲基甲酰胺)。X-射线单晶测试表明,这3个化合物均为2个以尾对尾方式排列的杯[8]芳烃分子中间夹1个3d-5f核簇的三明治型结构。杯[8]芳烃均表现为双锥式构型,且每个锥式空腔下缘结合1个钍离子,双锥的连接处及2个杯芳烃分子之间由过渡金属离子或钍离子连接。不同过渡金属离子不同的配位环境导致3种不同核簇的形成。化合物1的磁性研究表明,该化合物在低温下表现出弱铁磁性相互作用。

English

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  • 收稿日期:  2013-07-13
  • 网络出版日期:  2013-11-20
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