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RGO/C3N4复合材料的制备及可见光催化性能

张芬 ,  柴波 ,  廖翔 ,  任美霞 ,  柳兵仁

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引用本文: 张芬, 柴波, 廖翔, 任美霞, 柳兵仁. RGO/C3N4复合材料的制备及可见光催化性能[J]. 无机化学学报, 2014, 30(4): 821-827. doi: 10.11862/CJIC.2014.094 shu
Citation:  ZHANG Fen, CHAI Bo, LIAO Xiang, REN Mei-Xia, LIU Bing-Ren. Preparation and Visible Light Photocatalytic Properties of RGO/C3N4 Composites[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 821-827. doi: 10.11862/CJIC.2014.094 shu

RGO/C3N4复合材料的制备及可见光催化性能

    通讯作者: 柴波 willycb@163.com
  • 基金项目:

    武汉轻工大学引进(培养)人才科研启动项目(2012RZ12) (培养)人才科研启动项目(2012RZ12)

    武汉轻工大学大学生创新创业训练计划资助项目(No.CXXL2013009)。 (No.CXXL2013009)

摘要: 通过半封闭一步热裂解法和改进的Hummers法分别制备了类石墨氮化碳(C3N4)和氧化石墨烯(GO),再利用光还原方法制得还原氧化石墨烯/氮化碳(RGO/C3N4)复合材料。采用X射线衍射(XRD),场发射扫描电镜(FESEM),X射线光电子能谱(XPS),紫外-可见漫反射吸收光谱(DRS),光致荧光(PL)和傅里叶变换红外光谱(FTIR)等测试技术对复合材料进行表征。以罗丹明B(RhB)为探针分子在可见光下考察RGO/C3N4复合材料的光催化活性,结果表明：RGO的引入显著提高了C3N4的光催化活性,且6.0%RGO/C3N4复合物的光催化活性最高,可能的原因是RGO具有优良的接受和传导电子性能,抑制了C3N4光生电子-空穴的复合机率,进而提高了光催化活性。

English

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    1. [1] Hu X L, Li G S, Yu J C. Langmuir, 2010, 26:3031-3039[1] Hu X L, Li G S, Yu J C. Langmuir, 2010, 26:3031-3039

    2. [2] Chen C C, Ma W H, Zhao J C. Chem. Soc. Rev., 2010, 39: 4206-4219[2] Chen C C, Ma W H, Zhao J C. Chem. Soc. Rev., 2010, 39: 4206-4219

    3. [3] Chen X B, Shen S H, Guo L J, et al. Chem. Rev., 2010, 110: 6503-6570[3] Chen X B, Shen S H, Guo L J, et al. Chem. Rev., 2010, 110: 6503-6570

    4. [4] Lu S Y, Wu D, Wang Q L, et al. Chemosphere, 2011, 82: 1215-1224[4] Lu S Y, Wu D, Wang Q L, et al. Chemosphere, 2011, 82: 1215-1224

    5. [5] Chen X B, Mao S S. Chem. Rev., 2007, 107:2891-2959[5] Chen X B, Mao S S. Chem. Rev., 2007, 107:2891-2959

    6. [6] Wang H, Gao J, Guo T Q, et al. Chem. Commun., 2012, 48: 275-277[6] Wang H, Gao J, Guo T Q, et al. Chem. Commun., 2012, 48: 275-277

    7. [7] Bi Y P, Ouyan S X, Umezawa N, et al. J. Am. Chem. Soc., 2011, 133:6490-6492[7] Bi Y P, Ouyan S X, Umezawa N, et al. J. Am. Chem. Soc., 2011, 133:6490-6492

    8. [8] Shang M, Wang W Z, Zhang L. J. Hazard. Mater., 2009, 167: 803-809[8] Shang M, Wang W Z, Zhang L. J. Hazard. Mater., 2009, 167: 803-809

    9. [9] Yan S C, Li Z S, Zou Z G. Langmuir, 2009, 25:10397-10401[9] Yan S C, Li Z S, Zou Z G. Langmuir, 2009, 25:10397-10401

    10. [10] Liu J H, Zhang T K, Wang Z C, et al. J. Mater. Chem., 2011, 21:14398-14401[10] Liu J H, Zhang T K, Wang Z C, et al. J. Mater. Chem., 2011, 21:14398-14401

    11. [11] Cui Y J, Zhang J S, Zhang G G, et al. J. Mater. Chem., 2011, 21:13032-13039[11] Cui Y J, Zhang J S, Zhang G G, et al. J. Mater. Chem., 2011, 21:13032-13039

    12. [12] Ge L, Han C C, Liu J. Appl. Catal. B: Environ., 2011, 108 (109):100-107[12] Ge L, Han C C, Liu J. Appl. Catal. B: Environ., 2011, 108 (109):100-107

    13. [13] Sun J X, Yuan Y P, Qiu L G, et al. Dalton Trans., 2012, 41: 6756-6763[13] Sun J X, Yuan Y P, Qiu L G, et al. Dalton Trans., 2012, 41: 6756-6763

    14. [14] Cao S W, Yuan Y P, Fang J, et al. Int. J. Hydrogen Energy, 2013, 38:1258-1266[14] Cao S W, Yuan Y P, Fang J, et al. Int. J. Hydrogen Energy, 2013, 38:1258-1266

    15. [15] Chai B, Peng T Y, Mao J, et al. Phys. Chem. Chem. Phys., 2012, 14:16745-16752[15] Chai B, Peng T Y, Mao J, et al. Phys. Chem. Chem. Phys., 2012, 14:16745-16752

    16. [16] Dreyer D R, Park S, Bielawski C W, et al. Chem. Soc. Rev., 2010, 39:228-240[16] Dreyer D R, Park S, Bielawski C W, et al. Chem. Soc. Rev., 2010, 39:228-240

    17. [17] GENG Jing-Yi(耿静漪), ZHU Xin-Sheng(朱新生), DU Yu-Kou(杜玉扣). Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(2):357-361[17] GENG Jing-Yi(耿静漪), ZHU Xin-Sheng(朱新生), DU Yu-Kou(杜玉扣). Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(2):357-361

    18. [18] ZHOU Tian(周田), CHEN Bing-Di(陈炳地), YAO Ai-Hua (姚爱华), et al. Chinese. J. Inorg. Chem. (无机化学学报), 2013, 29(2):231-236[18] ZHOU Tian(周田), CHEN Bing-Di(陈炳地), YAO Ai-Hua (姚爱华), et al. Chinese. J. Inorg. Chem. (无机化学学报), 2013, 29(2):231-236

    19. [19] YING Hong(应红), WANG Zhi-Yong(王志永), GUO Zheng-Duo(郭政铎), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2011, 27(6):1482-1486[19] YING Hong(应红), WANG Zhi-Yong(王志永), GUO Zheng-Duo(郭政铎), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2011, 27(6):1482-1486

    20. [20] Xu T G, Zhang L W Cheng H Y, et al. Appl. Catal. B: Environ., 2011, 101:382-387[20] Xu T G, Zhang L W Cheng H Y, et al. Appl. Catal. B: Environ., 2011, 101:382-387

    21. [21] Xiang Q J, Yu J G, Jaroniec M. J. Phys. Chem. C, 2011, 115:7355-7363[21] Xiang Q J, Yu J G, Jaroniec M. J. Phys. Chem. C, 2011, 115:7355-7363

    22. [22] Liao G Z, Chen S, Quan X, et al. J. Mater. Chem., 2012, 22: 2721-2726[22] Liao G Z, Chen S, Quan X, et al. J. Mater. Chem., 2012, 22: 2721-2726

    23. [23] Zhang H, Fan X F, Quan X, et al. Environ. Sci. Technol., 2011, 45:5731-5736[23] Zhang H, Fan X F, Quan X, et al. Environ. Sci. Technol., 2011, 45:5731-5736

    24. [24] CHAI Bo(柴波), SONG Fa-Kun(宋发坤), ZHOU Huan (周欢), et al. J. Chinese. Ceram. Soc.(硅酸盐学报), 2013, 41 (4):560-566[24] CHAI Bo(柴波), SONG Fa-Kun(宋发坤), ZHOU Huan (周欢), et al. J. Chinese. Ceram. Soc.(硅酸盐学报), 2013, 41 (4):560-566

    25. [25] Shen J F, Yan B, Shi M, et al. J. Mater. Chem., 2011, 21: 3415-3421[25] Shen J F, Yan B, Shi M, et al. J. Mater. Chem., 2011, 21: 3415-3421

    26. [26] Cao J, Xu B Y, Lin H L, et al. Dalton Trans., 2012, 41: 11482-11490[26] Cao J, Xu B Y, Lin H L, et al. Dalton Trans., 2012, 41: 11482-11490

    27. [27] Cheng H F, Huang B B, Dai Y, et al. Langmuir, 2010, 26: 6618-6624[27] Cheng H F, Huang B B, Dai Y, et al. Langmuir, 2010, 26: 6618-6624

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  • 收稿日期:  2013-06-03
  • 网络出版日期:  2013-11-01
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