Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

Citation: Shu-sheng Li, Hui Han, Xiao-li Zhu, Xu-bao Jiang, Xiang Zheng Kong. Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal[J]. Chinese Journal of Polymer Science, 2015, 33(8): 1196-1210. doi: 10.1007/s10118-015-1670-7 shu

Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

1.
1. College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
2.
2. College of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
3.
4.
College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51473066, 21274054 and 21304038) and Science Technology Development Plans of Shandong Province, China (No. 2010GSF10610).

摘要: A novel and easy one-step protocol for preparation of a new porous material, polyurea (PPU), is reported, which is accomplished through a precipitation polymerization of toluene diisocyanate (TDI) in mixed solvent of H2O-acetone without need for surfactant and porogen. Effects of TDI concentration, mechanical stirring, solvent composition and TDI addition rate on PPU structure are studied. Surface morphology and pore structure of PPU are characterized by scanning electron microscopy and Hg intrusion. Chemical structure of the PPU polymer is investigated using NMR, XRD and FTIR. Mechanism of pore formation is discussed. The obtained PPU is used as adsorbent for anionic dyes adsorption investigation. Two anionic dyes, remazol brilliant blue R and acid fuchsine, are tested. The results indicate that the as-prepared PPU is of high performance in dye adsorption and recycled use. This study provided therefore a facile route to the preparation of a novel and attractive adsorbent candidate for removal of anionic dyes from wastewaters.

关键词:

English

Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

1.
1. College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
2.
2. College of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
3.
4.
College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
Received Date: 18 January 2015
Revised Date: 04 March 2015
Available Online: 05 August 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51473066, 21274054 and 21304038) and Science Technology Development Plans of Shandong Province, China (No. 2010GSF10610).

Abstract: A novel and easy one-step protocol for preparation of a new porous material, polyurea (PPU), is reported, which is accomplished through a precipitation polymerization of toluene diisocyanate (TDI) in mixed solvent of H2O-acetone without need for surfactant and porogen. Effects of TDI concentration, mechanical stirring, solvent composition and TDI addition rate on PPU structure are studied. Surface morphology and pore structure of PPU are characterized by scanning electron microscopy and Hg intrusion. Chemical structure of the PPU polymer is investigated using NMR, XRD and FTIR. Mechanism of pore formation is discussed. The obtained PPU is used as adsorbent for anionic dyes adsorption investigation. Two anionic dyes, remazol brilliant blue R and acid fuchsine, are tested. The results indicate that the as-prepared PPU is of high performance in dye adsorption and recycled use. This study provided therefore a facile route to the preparation of a novel and attractive adsorbent candidate for removal of anionic dyes from wastewaters.

Key words:

1. [1]
  Cheng, B., Le, Y., Cai, W. and Yu, J., J. Hazard. Mater., 2011, 185: 889
2. [2]
  Crini, G., Dyes Pigments, 2008, 77: 415
3. [3]
  Wang, S., Shi, X., Gan, Z. and Wang, F., Chinese J. Polym. Sci., 2015, 33(1): 128
4. [4]
  Wang, W., Pan, Y., Shi, K., Peng, C. and Ji, X., Chinese J. Polym. Sci., 2014, 32(12): 1646
5. [5]
  Wang, W., Peng, C., Shi, K., Pan, X., Zhang, H. and Ji, X., Chinese J. Polym. Sci., 2014, 32(12): 1639
6. [6]
  Rong, J., Ji, L. and Yang, Z., Chinese J. Polym. Sci., 2013, 31(9): 1204
7. [7]
  Liu, J., Yao, J., Wang, H. and Chan, K., Green Chem., 2006, 8: 386
8. [8]
  Samatya, S., Orhan, E., Kabay, N. and Tuncel, A., Colloid Surface A, 2010, 372: 102
9. [9]
  Han, L., Choi, H.J., Kim, D.K., Park, S.W., Liu, B. and Park, D.W., J. Mol. Catal. A, 2011, 338: 58
10. [10]
  Kitahara, K., Hirai, Y., Yoshihama, I., Hanada, T., Nagashima, K., Arai, S. and Yamashita, J., Anal. Sci., 2001, 17(Suppl.): i1225
11. [11]
  Slater, M., Snauko, M., Svec, F. and Frchet, M.J., Anal. Chem., 2006, 78: 4969
12. [12]
  Barahona, F., Turiel, E. and Martn-Esteban, A., J. Chromatogr. A, 2011, 1218: 7065
13. [13]
  Rabbani, M.G. and El-Kaderi, H.M., Chem. Mater., 2011, 23: 1650
14. [14]
  Gulfam, M., Lee, J.M., Kim, J., Lim, D.W., Lee, E.K. and Chung, B.G., Langmuir, 2011, 27: 10993
15. [15]
  Lewis, C.L., Lin, Y., Yang, C., Manocchi, A.K., Yuet, K.P., Doyle, P.S. and Yi, H., Langmuir, 2010, 26: 13436
16. [16]
  Liu, R., Liao, P., Liu, J. and Feng, P., Langmuir, 2011, 27: 3095
17. [17]
  Schnfeld, H., Hunger, K., Cecilia, R. and Kunz, U., Chem. Eng. J., 2004, 101: 455
18. [18]
  Zhang, Q., Saraf, L.V., Smith, J.R., Jha, P. and Hua, F., Sensor Actuat. A, 2009, 151: 154
19. [19]
  Liu, Q.Q., Wang, L., Xiao, A.G., Yu, H.J. and Tan, Q.H., Eur. Polym. J., 2008, 44: 2516
20. [20]
  Moustafa, A.B., Kahil, T. and Faizalla, A., J. Appl. Polym. Sci., 2000, 76: 594
21. [21]
  Xu, J., Chen, G., Yan, R., Wang, D., Zhang, M., Zhang, W. and Sun, P., Macromolecules, 2011, 44: 3730
22. [22]
  Kim, J.W. and Suh, K.D., J. Ind. Eng. Chem., 2008, 14: 1
23. [23]
  Prasath, R.A., Gokmen, M.T., Espeel, P. and Du Prez, F.E., Polym. Chem., 2010, 1: 685
24. [24]
  Li, X., Wang, X., Ye, G., Xia, W. and Wang, X., Polymer, 2010, 51: 860
25. [25]
  Yang, L., Li, Y., Jin, X., Ye, Z., Ma, X., Wang, L. and Liu, Y., Chem. Eng. J., 2011, 168: 115
26. [26]
  Dinu, M.V. and Dragan, E.S., React. Funct. Polym., 2008, 68: 1346
27. [27]
  Patel, H.A. and Yavuz, C.T., Chem. Commun., 2012, 48: 9989
28. [28]
  Kong, X.Z., Gu, X., Zhu, X. and Zhang, L., Macromol. Rapid Commun., 2009, 30: 909
29. [29]
  Jiang. W., Zhang, L., Gu, X., Zhu, X. and Kong, X.Z., Acta Polymerica Sinica (in Chinese), 2013, (3): 406
30. [30]
  Zhu, X., Zhang, L., Jiang, X. and Kong, X.Z., Acta Polymerica Sinica (in Chinese), 2013, (8): 1099
31. [31]
  Jiang, X., Kong, X.Z. and Zhu, X., J. Polym. Sci. A, 2011, 49: 4492
32. [32]
  Jiang, X., Zhu, X. and Kong, X.Z., Chem. Eng. J., 2012, 213: 214
33. [33]
  Xu, J., Han H., Zhang, L., Zhu, X., Jiang, X. and Kong, X.Z., RSC Adv., 2014, 4: 32134
34. [34]
  Han, H., Li, S., Zhu, X., Jiang, X. and Kong, X.Z., RSC Adv., 2014, 4: 33520
35. [35]
  Li, S., Jiang, X. and Kong, X.Z., Chem. J. Chin. Universities, 2013, 34(4): 992
36. [36]
  Lapprand, A., Boisson, F., Delolme, F., Mchin, F. and Pascault, J.P., Polym. Degrad. Stab., 2005, 90: 363
37. [37]
  Downey, J.S., Frank, R.S., Li, W.H. and Stver, H.D.H., Macromolecules, 1999, 32: 2838
38. [38]
  Gokmen, M.T. and Du Prez, F.E., Prog. Polym. Sci., 2012, 37: 365
39. [39]
  Wu, D., Xu, F., Sun B., Fu, R., He, H. and Matyjaszewski, K., Chem. Rev., 2012, 112: 3959
40. [40]
  Entelis, S.G. and Nesterov, O.V., Russ. Chem. Rev., 1966, 35: 917
41. [41]
  Kong, X.Z., Jiang, W., Jiang, X. and Zhu, X., Polym. Chem., 2013, 4: 5776
42. [42]
  Parlett, C.M.A., Wilson, K. and Lee, A.F., Chem. Soc. Rev., 2013, 42: 3876
43. [43]
  Cheng, G., Hasell, T., Trewin, A., Adams, D.J. and Cooper, A.I., Angew. Chem. Int. Ed., 2012, 51: 12727
44. [44]
  Allport, D.C., Gilbert, D.S. and Outterside, S.M., MDI and TDI: safety, health and the environment: a source book and practical guide, John Wiley Sons, Ltd, Chickester, UK, 2003, p. 237
45. [45]
  Pretsch, E., Biihlmann, P. and Affolter, C., Structure determination of organic compounds-tables of spectral data, 3rd Edn, Springer-Verlag, Berlin Heidelberg, 2000, p. 96
46. [46]
  Okuto, H., Die Makromol. Chem., 1966, 98: 148
47. [47]
  Luo, N., Wang, D.N. and Ying, S.K., Polymer, 1996, 37: 3577
48. [48]
  Feng, L.Q. and Iroh, J.O., Eur. Polym. J., 2013, 49: 1811
49. [49]
  Ishihara, H., Kimura, I. and Yoshihara, N., J. Macromol. Sci. Phys. B, 1983, 22: 713
50. [50]
  Arslan, M. and Yi?ito?lu, M., e-Polymers, 2007, 16: 1
51. [51]
  Wang, L. and Wang, A., Chem. Eng. J., 2008, 143: 43

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Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

English

Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

English

Preparation and Formation Mechanism of Porous Polyurea by Reaction of Toluene Diisocyanate with Water and Its Application as Adsorbent for Anionic Dye Removal

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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