Synthesis, Characterization and Optical Properties of Poly(aryleneethynylene)s Containing BODIPY

Bin Liu Fang-lin Huang Yong-feng Shi Zhi-qing Ni Ye Lin Shou-chun Yin

Citation:  Bin Liu, Fang-lin Huang, Yong-feng Shi, Zhi-qing Ni, Ye Lin, Shou-chun Yin. Synthesis, Characterization and Optical Properties of Poly(aryleneethynylene)s Containing BODIPY[J]. Chinese Journal of Polymer Science, 2015, 33(8): 1133-1139. doi: 10.1007/s10118-015-1664-5 shu

Synthesis, Characterization and Optical Properties of Poly(aryleneethynylene)s Containing BODIPY

    通讯作者: Shou-chun Yin,
  • 基金项目:

    The work was financially supported by the National Natural Science Foundation of China (Nos. 21174035 and 21274034).

摘要: Poly(aryleneethynylene)s containing BODIPY (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) (P1) were prepared by palladium-catalyzed Sonogashira polymerization of 2,6-diiodo-functionalized BODIPY monomer (M1) with 1,4-diethynyl-2,5-didodecyl-oxybenzene monomer (M2). The structures of the monomer (M1) and copolymer (P1) were confirmed by 1H-NMR and Fourier transform infrared (FTIR) spectroscopies; their optical properties were characterized by UV-Vis absorption, photoluminescence (PL) spectroscopy and the Z-scan technique. Both UV-Vis absorption and fluorescence emission of copolymer P1 red-shifted to longer wavelengths (abs: from 502 nm to 542 nm; em: from 511 nm to 631 nm) relative to those of the monomer M1 due to the -conjugation extension of the copolymer. The third-order nonlinear optical coefficient ((3)) of copolymer P1 was 1.9410-10 esu, which is almost two or three orders of magnitude greater than that of common conjugated polymers without BODPIY moiety.

English

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  • 发布日期:  2015-08-05
  • 收稿日期:  2014-11-29
  • 修回日期:  2014-12-31
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