Preparation and Properties of Poly(vinyl alcohol)/Chitosan Blend Bio-nanocomposites Reinforced by Cellulose Nanocrystals

Susan Azizi ,  Mansor Bin Ahmad ,  Nor Azow Ibrahim ,  Mohd Zobir Hussein ,  Farideh Namvar

Citation:  Susan Azizi, Mansor Bin Ahmad, Nor Azow Ibrahim, Mohd Zobir Hussein, Farideh Namvar. Preparation and Properties of Poly(vinyl alcohol)/Chitosan Blend Bio-nanocomposites Reinforced by Cellulose Nanocrystals[J]. Chinese Journal of Polymer Science, 2014, 32(12): 1620-1627. doi: 10.1007/s10118-014-1548-0 shu

Preparation and Properties of Poly(vinyl alcohol)/Chitosan Blend Bio-nanocomposites Reinforced by Cellulose Nanocrystals

    通讯作者: Susan Azizi, azisusan@gmail.com
  • 基金项目:

    This work was financially supported by Universiti Putra Malaysia (research grant RUGS 9199840), and the authors are grateful to staff of the Department of Chemistry UPM for their technical assistance.

摘要: The aim of this paper is to report the effect of the addition of cellulose nanocrystals (CNCs) on the mechanical, thermal and barrier properties of poly(vinyl alcohol)/chitosan (PVA/Cs) bio-nanocomposites films prepared through the solvent casting process. The characterizations of PVA/Cs/CNCs films were carried out in terms of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), thermogravimetric analysis (TGA and DTG), oxygen transmission rate (OTR), and tensile tests. TEM and SEM results showed that at low loading levels, CNCs were dispersed homogenously in the PVA/Cs matrix. The tensile strength and modulus in films increased from 55.1 MPa to 98.4 MPa and from 395 MPa to 690 MPa respectively, when CNCs content went from 0 wt% to 1.0 wt%. The thermal stability and oxygen barrier properties of PVA/Cs matrix were best enhanced at 1.0 wt% of CNCs loading. The enhanced properties attained by incorporating CNCs can be beneficial in various applications.

English


    1. [1]

      Fortunatia, E., Peltzer, M., Armentano, I., Torre, L., Jimnez, A. and Kenny. J.M., Carbohyd. Polym., 2012, 90: 948

    2. [2]

      Vicentini, D.S.V., Jr, A.S. and Mauro, C.M., Laranjeira. Mater. Sci. Eng. C., 2010, 30: 503

    3. [3]

      Yan, E., Fan, Sh., Li, X., Wang, C., Sun, Z., Ni, L. and Zhang, D., Mater. Sci. Eng., 2013, 33: 461

    4. [4]

      Kanikireddy, V., Murali, M.Y., Kokkarachedu, V., Nagireddy Narayana, R., Sakey, R., Neppalli Sudhakar, N. and Konduru Mohana, R., Acad. J., 2011, 2: 55

    5. [5]

      Parida, U.K., Nayak, A.K., Binhani, B.K. and Nayak, P.L., J. Biomater. Nanobiotechnol., 2011, 2: 414

    6. [6]

      Chandy, T. and Sharma, C.P., J. Appl. Polym. Sci., 1992, 44: 2145

    7. [7]

      Tang, X. and Alavi, S., Carbohydr. Polym., 2011, 85: 7

    8. [8]

      Pandey, K. and Singh, R.P., Biomacromolecules., 2001, 2: 880

    9. [9]

      Cao, X.D., Dong, H. and Li, C.M., Biomacromolecules., 2007, 8: 899

    10. [10]

      Samir, M.A.S.A., Alloin, F. and Dufresne, A., Biomacromolecules., 2005, 6: 612

    11. [11]

      Azizi, S., Ahmad, M.B., Hussein, M.Z. and Ibrahim, N.A., Molecules., 2013, 18: 6269

    12. [12]

      Fortunati, E., Armentano, I., Zhou, Q., Iannoni, A., Saino, E., Visai, L., Berglund, L.A. and Kenny, J.M., Carboyd. Polym., 2012, 87: 1596

    13. [13]

      Habibi, Y., Lucia, L.A. and Rojas, O.J., Chem. Rev., 2010, 110: 3479

    14. [14]

      Dong, X.M., Revol, J.F. and Gray, D.G., Cellulose., 1998, 5: 19

    15. [15]

      Xu, W., Qin, Z.Y., Yu, H.Y., Liu, Y., Liu, N., Zhou, Z. and Chen, L., J. Nanopart. Res., 2013, 15: 1562

    16. [16]

      Yu, H.Y, Qin, Z.Y., Liang, B.L., Liu, N., Zhou, Z. and Chen, L., J. Mater. Chem. A., 2013, 1: 3938

    17. [17]

      Noishiki, Y., Nishiyama, Y., Wada, M., Kuga, S. and Magoshi, J., J. Appl. Polym. Sci., 2001, 86: 3425

    18. [18]

      Grunert, M.W.W., J. Polym. Environ., 2002, 10: 27

    19. [19]

      Kvien, I., Sugiyama, J., Votrubec, M. and Oksman, K., J. Mater. Sci., 2007, 42: 1573

    20. [20]

      Bhatanager, A. and Sain, M., J. Reinf. Plast. Compos., 2005, 24: 1259

    21. [21]

      Wang, B. and Sain, M., Polym. Int., 2007, 56: 538

    22. [22]

      Pandey, J.K., Chu, W.S., Kim, C.S., Lee, C.S. and Ahn, S.H., Composites Part. B., 2009, 40: 676

    23. [23]

      Kim, D.W., Park, K.W., Chowdhury , S.R. and Kim, G.H., J. Appl. Polym. Sci., 2006,102: 3259

    24. [24]

      Perez, C.J., Alvarez, V.A., Mondragon, I. and Vazquez, A., Polym. Int. 2007, 56: 686

    25. [25]

      Liang, S., Liu, L., Huang, Q. and Yam, K.L., Carbohydr. Polym., 2009, 77: 718

    26. [26]

      Wang, Q., Du, Y.M. and Fan, L.H. J. Appl. Polym. Sci. 2005, 96: 808

    27. [27]

      Beck-Candanedo, S., Roman, M. and Gray, D.G., Biomacromolecules., 2005, 6: 1048

    28. [28]

      Costa-Jnior, E.S., Barbosa-Stancioli, E.F., Mansur, A.A.P., Vasconcelos, W.L. and Mansur, H.S., Carbohyd. Polym., 2009, 76: 472

    29. [29]

      Yamada, M. and Honma, I., Electrochim. Acta, 2005, 50: 2837

    30. [30]

      Dufresne, A., Can. J. Chem., 2008, 86: 484

    31. [31]

      Eichhorn, S.J. and Defense, A., J. Mater. Sci. Lett., 2010, 45: 1

    32. [32]

      Rueda, L., Saralegui, A., Fernndezd'Arlas, B., Zhou, Q., Berglund, L.A., Coreuera, M.A. and Eceiza, M.A., Carbohyd. Polym., 2013, 92:751

    33. [33]

      Favier, V., Chanzy, H. and Cavaille, J.Y., Macromolecules, 1996, 28: 6365

    34. [34]

      Kanagaraj, S., Varanda, F.R., Zhil'tsova, T.V., Oliveira, M.S. and Simes, J.A.O., Compos. Sci. Technol., 2007, 67: 3071

    35. [35]

      Savadekar, N.R. and Mhaske. S.T., Carbohydr. Polym., 2012, 89: 146

    36. [36]

      Azeredo, H.M., Mattoso, L.H., Avena-Bustillos, R.J.A., Filho, G.C., Munford, M.L., Wood, D. and Mchugh, T.H., J. Food. Sci., 2010, 75: 19

    37. [37]

      Ma, X.Y. and Zhang W.D., Polym. Degrad. Stab., 2009, 94: 1103

    38. [38]

      Kuo, S.W., J. Polym. Res., 2008, 15: 459

    39. [39]

      Paralikar, S.A., Simonsen, J. and Lombardi, J., J. Membr. Sci., 2008, 320: 248

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  • 发布日期:  2014-12-05
  • 收稿日期:  2014-03-05
  • 修回日期:  2014-05-29
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