Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers

注册 English

Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers

Jian Jiang , Wei Yan , Ling-yan Liu , Wei-xing Chang , Jing Li

Citation: Jian Jiang, Wei Yan, Ling-yan Liu, Wei-xing Chang, Jing Li. Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers[J]. Chinese Journal of Polymer Science, 2014, 32(12): 1655-1665. doi: 10.1007/s10118-014-1546-2 shu

shu

Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers

1.
The State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21072099, 21202084 and 21372120).

摘要: A tin-oxygen coordination driving self-assembly was developed in the block copolymers containing organotin, which were prepared by the radical addition-fraction transfer (RAFT) method and characterized by the gel-permeation chromatography (GPC) and 1H-NMR. And the self-assemblies of these block copolymers with various chain length ratios in the different concentrations in CHCl3 were stable according to the results of DLS and TEM. Additionally, it was also given an insight investigation on the regulation of self-assembly of the block copolymers by adding dibutyltin dichloride and a possible mechanism was proposed.

关键词:

English

Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers

1.
The State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China
Received Date: 24 March 2014
Revised Date: 13 May 2014
Available Online: 05 December 2014
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21072099, 21202084 and 21372120).

Abstract: A tin-oxygen coordination driving self-assembly was developed in the block copolymers containing organotin, which were prepared by the radical addition-fraction transfer (RAFT) method and characterized by the gel-permeation chromatography (GPC) and 1H-NMR. And the self-assemblies of these block copolymers with various chain length ratios in the different concentrations in CHCl3 were stable according to the results of DLS and TEM. Additionally, it was also given an insight investigation on the regulation of self-assembly of the block copolymers by adding dibutyltin dichloride and a possible mechanism was proposed.

Key words:

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