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Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4, 5-dicarboxylate

Li-Zhuang Chen ,  Deng-Deng Huang

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Citation:  Li-Zhuang Chen, Deng-Deng Huang. Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4, 5-dicarboxylate[J]. Chinese Chemical Letters, 2014, 25(2): 279-282. shu

Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4, 5-dicarboxylate

    • 通讯作者: Li-Zhuang Chen,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No. 21201087) (No. 21201087)

    the Foundation of Jiangsu Educational Committee (No. 11KJB150004) (No. 11KJB150004)

摘要: A new Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate (H3PIDC) has been synthesized under hydrothermal conditions, formulated as {[Gd3(HPIDC)3(PIDC)(H2O)4]·3H2O}n (1). The compound crystallizes in the monoclinic system, space group C2/c with a = 20.951(7), b = 9.515(3), c = 27.483(10)Å, β = 106.176(6)°, Z = 4, V = 5262(3)Å3, C40H45Gd3N12O30, Dc = 2.071 g/cm3, Mr = 1645.63, λ (MoKa) = 0.71073Å, μ = 3.846 mm-1, F(000) = 3204, the final R = 0.0390 and wR = 0.1332. Complex 1 is a two-dimensional MOF built up from T-shaped 3-connected HPIDC2-, PIDC3- and 4-connected metal nodes. Dielectric constant of complex 1 was measured at different frequencies with temperature variation.

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  • 收稿日期:  2013-10-22
  • 网络出版日期:  2013-11-11
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