引用本文:
Jin Tang DU, Yan Mei LI, Zhong Zhou CHEN, Shi Zhong LUO, Yu Fen ZHAO. The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative[J]. Chinese Chemical Letters,
2005, 16(7): 856-858.
Citation: Jin Tang DU, Yan Mei LI, Zhong Zhou CHEN, Shi Zhong LUO, Yu Fen ZHAO. The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative[J]. Chinese Chemical Letters, 2005, 16(7): 856-858.
Citation: Jin Tang DU, Yan Mei LI, Zhong Zhou CHEN, Shi Zhong LUO, Yu Fen ZHAO. The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative[J]. Chinese Chemical Letters, 2005, 16(7): 856-858.
The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative
摘要:
O-Phosphoryl serine derivative can perform self-catalytic esterification reaction in the mixture of CH3OH and CHCl3 at the room temperature. The phosphoryl group participation was the key step of the esterification. This type of reactions were proposed through an intermediate of mixed phosphoric-carboxylic anhydride that might provide a clue to the function of the phosphoryl group in the phosphorylated enzymes and in the prebiotic synthesis of protein.
English
The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative
Abstract:
O-Phosphoryl serine derivative can perform self-catalytic esterification reaction in the mixture of CH3OH and CHCl3 at the room temperature. The phosphoryl group participation was the key step of the esterification. This type of reactions were proposed through an intermediate of mixed phosphoric-carboxylic anhydride that might provide a clue to the function of the phosphoryl group in the phosphorylated enzymes and in the prebiotic synthesis of protein.
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Key words:
- O-Phosphoryl serine
- / self esterification
- / phosphoryl group participation
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