引用本文:
Jing Lin CHEN, Gang Qiang YIN, Zhong Ning CHEN. Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru3ш(μ3-O)(μ-CH3COO)6(py)2Cl with Four Steps One-electron Redox Processes[J]. Chinese Chemical Letters,
2003, 14(5): 519-522.
Citation: Jing Lin CHEN, Gang Qiang YIN, Zhong Ning CHEN. Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru3ш(μ3-O)(μ-CH3COO)6(py)2Cl with Four Steps One-electron Redox Processes[J]. Chinese Chemical Letters, 2003, 14(5): 519-522.
Citation: Jing Lin CHEN, Gang Qiang YIN, Zhong Ning CHEN. Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru3ш(μ3-O)(μ-CH3COO)6(py)2Cl with Four Steps One-electron Redox Processes[J]. Chinese Chemical Letters, 2003, 14(5): 519-522.
Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru3ш(μ3-O)(μ-CH3COO)6(py)2Cl with Four Steps One-electron Redox Processes
摘要:
The synthesis and crystal structure of oxo-centered carboxylate-bridge trinuclear ruthenium complex, Ru3O(CH3COO)6(py)2Cl (py =pyridine) (1), are reported herein.The complex 1 has been characterized by IR, cyclic voltammetry (CV), UV-Vis and X-ray crystal analysis.The complex 1 in 0.1 mol/L (n-C4H9)4NPF6-CH2Cl2 solution at room temperature shows four one-electron redox processes at E1/2=-1.38,-1.20,-0.17 and 1.07 V vs.Ag/AgCl.
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关键词:
- Crystal structure
- / ruthenium
- / carboxylate
- / electrochemistry
English
Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru3ш(μ3-O)(μ-CH3COO)6(py)2Cl with Four Steps One-electron Redox Processes
Abstract:
The synthesis and crystal structure of oxo-centered carboxylate-bridge trinuclear ruthenium complex, Ru3O(CH3COO)6(py)2Cl (py =pyridine) (1), are reported herein.The complex 1 has been characterized by IR, cyclic voltammetry (CV), UV-Vis and X-ray crystal analysis.The complex 1 in 0.1 mol/L (n-C4H9)4NPF6-CH2Cl2 solution at room temperature shows four one-electron redox processes at E1/2=-1.38,-1.20,-0.17 and 1.07 V vs.Ag/AgCl.
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Key words:
- Crystal structure
- / ruthenium
- / carboxylate
- / electrochemistry
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