Modulation of Electrochemical Oscillations by Specific Adsorption of Cl-during the Electrooxidation of Methanol on Pt Electrode

Ze Lin LI Ji Hua HUANG Xiao Ming XIAO Yue ZENG Xia CHU

引用本文: Ze Lin LI,  Ji Hua HUANG,  Xiao Ming XIAO,  Yue ZENG,  Xia CHU. Modulation of Electrochemical Oscillations by Specific Adsorption of Cl-during the Electrooxidation of Methanol on Pt Electrode[J]. Chinese Chemical Letters, 2002, 13(3): 277-278. shu
Citation:  Ze Lin LI,  Ji Hua HUANG,  Xiao Ming XIAO,  Yue ZENG,  Xia CHU. Modulation of Electrochemical Oscillations by Specific Adsorption of Cl-during the Electrooxidation of Methanol on Pt Electrode[J]. Chinese Chemical Letters, 2002, 13(3): 277-278. shu

Modulation of Electrochemical Oscillations by Specific Adsorption of Cl-during the Electrooxidation of Methanol on Pt Electrode

  • 基金项目:

    Financial support by the National Natural Science Foundation of China (20073012) is gratefully acknowledged.

摘要: Potential oscillation during the electrocatalytic oxidation of methanol can be modulated by the specific adsorption of Cl- on the platinum electrode, which suppresses the electrocatalytic oxidation of methanol, and makes the cross cycle in the cyclic voltammogram become smaller and finally disappear with the increase of Cl- concentration. The method is also applicable to the electrocatalytic oxidation of other small organic molecules.

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  • 收稿日期:  2001-06-18
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