A Novel Method to Synthesize Polyorganozircosilazane

Chun Juan LIU Li Hua LIU Shi Yan YANG Wei GAO Ze Min XIE

引用本文: Chun Juan LIU,  Li Hua LIU,  Shi Yan YANG,  Wei GAO,  Ze Min XIE. A Novel Method to Synthesize Polyorganozircosilazane[J]. Chinese Chemical Letters, 2002, 13(12): 1225-1226. shu
Citation:  Chun Juan LIU,  Li Hua LIU,  Shi Yan YANG,  Wei GAO,  Ze Min XIE. A Novel Method to Synthesize Polyorganozircosilazane[J]. Chinese Chemical Letters, 2002, 13(12): 1225-1226. shu

A Novel Method to Synthesize Polyorganozircosilazane

  • 基金项目:

    We gratefully acknowledge the National Natural Sciences Foundation of China (No.50072033) for the financial support.

摘要: A new kind of polyorganozircosilazane as Si/Zr/C/N-based ceramic precursor was synthesized from the condensation reaction of hexamethylcyclotrisilazane lithium salts (D3NLi) and zirconium tetrachloride (ZrCl4). In the presence of N, N, N', N'-tetramethyl ethylene diamine (TMEDA), polyorganozircosilazane was obtained in high yield.

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  • 收稿日期:  2002-02-22
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