引用本文:
Jian Kui ZHAO, Yan Guang WANG. A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides[J]. Chinese Chemical Letters,
2002, 13(12): 1149-1151.
Citation: Jian Kui ZHAO, Yan Guang WANG. A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides[J]. Chinese Chemical Letters, 2002, 13(12): 1149-1151.
Citation: Jian Kui ZHAO, Yan Guang WANG. A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides[J]. Chinese Chemical Letters, 2002, 13(12): 1149-1151.
A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides
摘要:
Catalytic amination of aryl bromides with in situ generated dimethylamines from N,N-dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields.
English
A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides
Abstract:
Catalytic amination of aryl bromides with in situ generated dimethylamines from N,N-dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields.
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Key words:
- Amination
- / nickel-catalyzed
- / cross-coupling reaction
- / N,N-dimethylarylamine
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