High-Yield Synthesis of Endohedral Metallofullerenes Y@C2n and Y2@C2n

Yong Fu LIAN Zu Jin SHI Xi Huang ZHOU Xiao Ran HE Zhen Nan GU

引用本文: Yong Fu LIAN,  Zu Jin SHI,  Xi Huang ZHOU,  Xiao Ran HE,  Zhen Nan GU. High-Yield Synthesis of Endohedral Metallofullerenes Y@C2n and Y2@C2n[J]. Chinese Chemical Letters, 1999, 10(5): 425-428. shu
Citation:  Yong Fu LIAN,  Zu Jin SHI,  Xi Huang ZHOU,  Xiao Ran HE,  Zhen Nan GU. High-Yield Synthesis of Endohedral Metallofullerenes Y@C2n and Y2@C2n[J]. Chinese Chemical Letters, 1999, 10(5): 425-428. shu

High-Yield Synthesis of Endohedral Metallofullerenes Y@C2n and Y2@C2n

  • 基金项目:

    This work is supported by the National Natural Science Foundation of China. No. 295.

摘要: A series of yttrium metallofullerenes. some of them are first reported. have been synthesized by the DC arc discharge method at high helium pressure. Mass spectra results show that the contents of metallofullerenes are very high both in primary soot and in CS2 or DMF extract and Y@C82 with ca. 85% purity is obtained through column chromatographic isolation.

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  • 收稿日期:  1998-12-03
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