引用本文:
Yao Yu WANG, Xin WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO. Studies on A Novel Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Imidazole and Aqua[J]. Chinese Chemical Letters,
1999, 10(2): 187-188.
Citation: Yao Yu WANG, Xin WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO. Studies on A Novel Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Imidazole and Aqua[J]. Chinese Chemical Letters, 1999, 10(2): 187-188.
Citation: Yao Yu WANG, Xin WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO. Studies on A Novel Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Imidazole and Aqua[J]. Chinese Chemical Letters, 1999, 10(2): 187-188.
Studies on A Novel Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Imidazole and Aqua
摘要:
A novel mixed-valence copper (I, II) complex Cu3 [CH2=C(CH3) COO]5 (imH)3 (H2O) has been synthesized and characterised by XPS spectra and single crystal X-ray structural analysis The title complex crystallized in monoclinic space group P21/c, with a=11.225 (3), b=13.9023 (12) c=24.559 (2)Å, β=92.372 (10)° and Z=4. Final R=0.0495 for 5546 reflections [I>2σ(I)].
English
Studies on A Novel Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Imidazole and Aqua
Abstract:
A novel mixed-valence copper (I, II) complex Cu3 [CH2=C(CH3) COO]5 (imH)3 (H2O) has been synthesized and characterised by XPS spectra and single crystal X-ray structural analysis The title complex crystallized in monoclinic space group P21/c, with a=11.225 (3), b=13.9023 (12) c=24.559 (2)Å, β=92.372 (10)° and Z=4. Final R=0.0495 for 5546 reflections [I>2σ(I)].
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Key words:
- Mixed-valence copper (Ⅰ,Ⅱ) complex
- / synthesis
- / crystal structure
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