引用本文:
Yu LIU, Yi Min ZHANG, Yun Ti CHEN. SYNTHESIS AND CHARACTERIZATION OF NOVEL FUNCTIONAL HOST COMPOUND 2[1] MONO-[6-O-(8-QUINOLYL)]-β-CYCLODEXTRIN[J]. Chinese Chemical Letters,
1996, 7(6): 523-526.
Citation: Yu LIU, Yi Min ZHANG, Yun Ti CHEN. SYNTHESIS AND CHARACTERIZATION OF NOVEL FUNCTIONAL HOST COMPOUND 2[1] MONO-[6-O-(8-QUINOLYL)]-β-CYCLODEXTRIN[J]. Chinese Chemical Letters, 1996, 7(6): 523-526.
Citation: Yu LIU, Yi Min ZHANG, Yun Ti CHEN. SYNTHESIS AND CHARACTERIZATION OF NOVEL FUNCTIONAL HOST COMPOUND 2[1] MONO-[6-O-(8-QUINOLYL)]-β-CYCLODEXTRIN[J]. Chinese Chemical Letters, 1996, 7(6): 523-526.
SYNTHESIS AND CHARACTERIZATION OF NOVEL FUNCTIONAL HOST COMPOUND 2[1] MONO-[6-O-(8-QUINOLYL)]-β-CYCLODEXTRIN
摘要:
A novel β-cyclodextrin (β-CD) derivative (2) bearing a single 8-quinolyl moiety has been synthesized by a convenient method in 41.4% yield,and the compound was characterized by 1H-NMR,FT-IR spectra and elemental analysis,etc.The spectrophotometric titrations have been performed in buffered aqueous solution (pH=7.20) to give the complex stability constants (K) and Gibbs free energy changes (-△G·) for the 1:1 inclusion complexation of some amino acids guest molecules with host compound (2) and mono-(6-anilino)-β-cyclodextrin (1).
English
SYNTHESIS AND CHARACTERIZATION OF NOVEL FUNCTIONAL HOST COMPOUND 2[1] MONO-[6-O-(8-QUINOLYL)]-β-CYCLODEXTRIN
Abstract:
A novel β-cyclodextrin (β-CD) derivative (2) bearing a single 8-quinolyl moiety has been synthesized by a convenient method in 41.4% yield,and the compound was characterized by 1H-NMR,FT-IR spectra and elemental analysis,etc.The spectrophotometric titrations have been performed in buffered aqueous solution (pH=7.20) to give the complex stability constants (K) and Gibbs free energy changes (-△G·) for the 1:1 inclusion complexation of some amino acids guest molecules with host compound (2) and mono-(6-anilino)-β-cyclodextrin (1).
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