SYNTHESIS OF PROPYLENE GLYCOL AND DIMETHYL CARBONATE USING POLYMER-SUPPORTED CATALYSTS

Hong ZHU ,  Li Ban CHEN ,  Ying Yan JIANG

引用本文: Hong ZHU,  Li Ban CHEN,  Ying Yan JIANG. SYNTHESIS OF PROPYLENE GLYCOL AND DIMETHYL CARBONATE USING POLYMER-SUPPORTED CATALYSTS[J]. Chinese Chemical Letters, 1996, 7(6): 519-522. shu
Citation:  Hong ZHU,  Li Ban CHEN,  Ying Yan JIANG. SYNTHESIS OF PROPYLENE GLYCOL AND DIMETHYL CARBONATE USING POLYMER-SUPPORTED CATALYSTS[J]. Chinese Chemical Letters, 1996, 7(6): 519-522. shu

SYNTHESIS OF PROPYLENE GLYCOL AND DIMETHYL CARBONATE USING POLYMER-SUPPORTED CATALYSTS

  • 基金项目:

    We thank the National Science Foundation of China for financial support.

摘要: Two types of effective transesterification catalysts including ordinary anion exchange resins and polymer-supported triphenyl phosphines are used to synthesize propylene glycol and dimethyl carbonate from propylene carbonate and methanol.The experimental results show that the products can be obtained under moderate conditions using these catalysts.Triphenyl phosphine polymeric catalysts are found thermally stable by thermogravimetry (TG).

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  • 收稿日期:  1995-10-09
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