Studies of artificial Hydrolytic metalloenzymes The catalytic carboxyester hydrolysis by novel nucleophile containing phenolic pendant macrocyclic polyamines

Wan Dong CHEN Xiang Chen YIN Shou Rong ZHU Hua Kuan LIN Fu Ping KOU Chun Chen LIN Mei Rong LIN Yun Ti CHEN

引用本文: Wan Dong CHEN,  Xiang Chen YIN,  Shou Rong ZHU,  Hua Kuan LIN,  Fu Ping KOU,  Chun Chen LIN,  Mei Rong LIN,  Yun Ti CHEN. Studies of artificial Hydrolytic metalloenzymes The catalytic carboxyester hydrolysis by novel nucleophile containing phenolic pendant macrocyclic polyamines[J]. Chinese Chemical Letters, 1996, 7(11): 979-980. shu
Citation:  Wan Dong CHEN,  Xiang Chen YIN,  Shou Rong ZHU,  Hua Kuan LIN,  Fu Ping KOU,  Chun Chen LIN,  Mei Rong LIN,  Yun Ti CHEN. Studies of artificial Hydrolytic metalloenzymes The catalytic carboxyester hydrolysis by novel nucleophile containing phenolic pendant macrocyclic polyamines[J]. Chinese Chemical Letters, 1996, 7(11): 979-980. shu

Studies of artificial Hydrolytic metalloenzymes The catalytic carboxyester hydrolysis by novel nucleophile containing phenolic pendant macrocyclic polyamines

摘要: Zinc(Ⅱ)complexes of new macrocyclic tetraamines(cyclam derivatives)having a strategically appended phenolate group,have been examined as catalyst for the hydrolysis of 4-nitrophenyl acetate(NA).It was proven that coordinated phenolate can serve as a good nucleophile that efficiently catalyze 4-nitrophenyl acetate(NA)hydrolysis.

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  • 收稿日期:  1996-03-11
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