引用本文:
Tie Jun WANG, Zhao Hui MA, Mei Yu HUANG, Ying Yan JIANG. ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX[J]. Chinese Chemical Letters,
1996, 7(1): 47-50.
Citation: Tie Jun WANG, Zhao Hui MA, Mei Yu HUANG, Ying Yan JIANG. ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX[J]. Chinese Chemical Letters, 1996, 7(1): 47-50.
Citation: Tie Jun WANG, Zhao Hui MA, Mei Yu HUANG, Ying Yan JIANG. ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX[J]. Chinese Chemical Letters, 1996, 7(1): 47-50.
ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX
摘要:
Silica immobilized N,N'-bis[-2-(benzimidazolylmethyl)]amino-ferrous acetate complexes (Ⅳ) catalyzed monooxygenation of cyclohexane to cyclohexanol with the turnover number 8.4 (equivalent C%=11.2) under mild conditions.The methylene blue is the most effective electron transfer agent which can also regulate products distribution.The iron content of the polymer-supported complexes,the redox potentials and the concentration of methylene blue greatly affect the activity and selectivity of the complex (Ⅳ).
English
ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX
Abstract:
Silica immobilized N,N'-bis[-2-(benzimidazolylmethyl)]amino-ferrous acetate complexes (Ⅳ) catalyzed monooxygenation of cyclohexane to cyclohexanol with the turnover number 8.4 (equivalent C%=11.2) under mild conditions.The methylene blue is the most effective electron transfer agent which can also regulate products distribution.The iron content of the polymer-supported complexes,the redox potentials and the concentration of methylene blue greatly affect the activity and selectivity of the complex (Ⅳ).
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