引用本文:
Pang CHENG, Dai Zheng LIAO, Shi Ping YAN, Zong Hui JIANG, Geng Liu WANG. PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL[J]. Chinese Chemical Letters,
1995, 6(7): 641-644.
Citation: Pang CHENG, Dai Zheng LIAO, Shi Ping YAN, Zong Hui JIANG, Geng Liu WANG. PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL[J]. Chinese Chemical Letters, 1995, 6(7): 641-644.
Citation: Pang CHENG, Dai Zheng LIAO, Shi Ping YAN, Zong Hui JIANG, Geng Liu WANG. PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL[J]. Chinese Chemical Letters, 1995, 6(7): 641-644.
PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL
摘要:
Four new binuclear copper(Ⅱ)complexes[Cu2(L)(μ-X)]have been synthesized and characterized, where X=C6H5COO(1), C2H5COO(2), pyrazolate(C3H3N2)(3)and 1, 3-N3(4).The ligand H3L is a 2:1 Schiff base derived from 2-hydroxy-1-naphthaldehyde and 1, 3-diamino-2-propanol.The variable temperature magnetic analyses show that complexes(1), (2)and(3)are paramagnetic with 2J=-158~-188 cm-1, and complex(4)is diamagnetic with|2J|>1000 cm-1.
English
PARAMAGNETIC AND DIAMAGNETIC DICOPPER(Ⅱ) COMPLEXES WITH DI-SCHIFF BASE DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND1, 3-DIANINO-2-PROPANOL
Abstract:
Four new binuclear copper(Ⅱ)complexes[Cu2(L)(μ-X)]have been synthesized and characterized, where X=C6H5COO(1), C2H5COO(2), pyrazolate(C3H3N2)(3)and 1, 3-N3(4).The ligand H3L is a 2:1 Schiff base derived from 2-hydroxy-1-naphthaldehyde and 1, 3-diamino-2-propanol.The variable temperature magnetic analyses show that complexes(1), (2)and(3)are paramagnetic with 2J=-158~-188 cm-1, and complex(4)is diamagnetic with|2J|>1000 cm-1.
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