引用本文:
Chuan Fang ZHU, Hai Yan XIAO. TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES[J]. Chinese Chemical Letters,
1995, 6(7): 565-568.
Citation: Chuan Fang ZHU, Hai Yan XIAO. TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES[J]. Chinese Chemical Letters, 1995, 6(7): 565-568.
Citation: Chuan Fang ZHU, Hai Yan XIAO. TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES[J]. Chinese Chemical Letters, 1995, 6(7): 565-568.
TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES
摘要:
By refluxing with cuprous halides in acetonitrile trialkyl phosphites can be directly converted into the corresponding dialkyl alkylphosphonate.The conversion of trialkyl phosphites with cuprous iodide is more favorable than with cuprous chloride;The activity of the alkyl group for the rearrangement is in the order of Me> Et> butyl.
English
TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES
Abstract:
By refluxing with cuprous halides in acetonitrile trialkyl phosphites can be directly converted into the corresponding dialkyl alkylphosphonate.The conversion of trialkyl phosphites with cuprous iodide is more favorable than with cuprous chloride;The activity of the alkyl group for the rearrangement is in the order of Me> Et> butyl.
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