引用本文:
Yun Ti CHEN, Heng Qian LIU, Jing Jiang LIU, Xian He BU, Jin Ling WANG, Li Juan ZHANG, Fang Ming MIAO. STUDY ON THE STRUCTURES OF COORDINATION COMPOUNDS OF N-(ortho-METHYL)-AND N-(ortho-METHOXY)-PHENYL IMINODIACETATO-Cu(II)[J]. Chinese Chemical Letters,
1991, 2(4): 317-320.
Citation: Yun Ti CHEN, Heng Qian LIU, Jing Jiang LIU, Xian He BU, Jin Ling WANG, Li Juan ZHANG, Fang Ming MIAO. STUDY ON THE STRUCTURES OF COORDINATION COMPOUNDS OF N-(ortho-METHYL)-AND N-(ortho-METHOXY)-PHENYL IMINODIACETATO-Cu(II)[J]. Chinese Chemical Letters, 1991, 2(4): 317-320.
Citation: Yun Ti CHEN, Heng Qian LIU, Jing Jiang LIU, Xian He BU, Jin Ling WANG, Li Juan ZHANG, Fang Ming MIAO. STUDY ON THE STRUCTURES OF COORDINATION COMPOUNDS OF N-(ortho-METHYL)-AND N-(ortho-METHOXY)-PHENYL IMINODIACETATO-Cu(II)[J]. Chinese Chemical Letters, 1991, 2(4): 317-320.
STUDY ON THE STRUCTURES OF COORDINATION COMPOUNDS OF N-(ortho-METHYL)-AND N-(ortho-METHOXY)-PHENYL IMINODIACETATO-Cu(II)
摘要:
The coordination compounds,{Cu[CH3C6H4N(CH2COO)2]}·2H2O and {Cu[CH3OC6H4N(CH2COO)2]}·2H2O,have been prepared and its crystal structures determined.The final discrepancy factors are R=0.052,Rw=0.061 for(I)and R=0.052,Rw=0.039 for(Ⅱ).The geometry of the coordination polyhedron with Cu(Ⅱ)is a distorted tetragonal pyramid for(Ⅰ)and an unsymmetrical and extended tetragonal bipyramid for(Ⅱ),respectively.The results of EHMO calculations indicate that the ligand mainly provided the field with very few of its electrons being coordinated to the central atom.
English
STUDY ON THE STRUCTURES OF COORDINATION COMPOUNDS OF N-(ortho-METHYL)-AND N-(ortho-METHOXY)-PHENYL IMINODIACETATO-Cu(II)
Abstract:
The coordination compounds,{Cu[CH3C6H4N(CH2COO)2]}·2H2O and {Cu[CH3OC6H4N(CH2COO)2]}·2H2O,have been prepared and its crystal structures determined.The final discrepancy factors are R=0.052,Rw=0.061 for(I)and R=0.052,Rw=0.039 for(Ⅱ).The geometry of the coordination polyhedron with Cu(Ⅱ)is a distorted tetragonal pyramid for(Ⅰ)and an unsymmetrical and extended tetragonal bipyramid for(Ⅱ),respectively.The results of EHMO calculations indicate that the ligand mainly provided the field with very few of its electrons being coordinated to the central atom.
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