引用本文:
Jing Jiang LIU, Gua Lin DUAN, Xiao Tian Liang. AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES[J]. Chinese Chemical Letters,
1991, 2(3): 245-248.
Citation: Jing Jiang LIU, Gua Lin DUAN, Xiao Tian Liang. AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES[J]. Chinese Chemical Letters, 1991, 2(3): 245-248.
Citation: Jing Jiang LIU, Gua Lin DUAN, Xiao Tian Liang. AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES[J]. Chinese Chemical Letters, 1991, 2(3): 245-248.
AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES
摘要:
Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo-del moleeule CH3-O-O-CH3. For P form when 0° ≤θ (twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°< θ ≤180°, there is negative Cotton effect;the curve is bisignate at θ=90°.
English
AN AB INITIO STU DY ON THE CORELATION BETWEEN THE ABSOLUTE CONFIGURATION AND THE CD SPECTRA OF ORGANIC PEROXIDES
Abstract:
Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo-del moleeule CH3-O-O-CH3. For P form when 0° ≤θ (twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°< θ ≤180°, there is negative Cotton effect;the curve is bisignate at θ=90°.
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