引用本文:
姜艳, 汪信, 孙小强, 王云翔. 一种含三嗪单元多齿手性配体的合成[J]. 应用化学,
2009, 26(11): 1371-1373.
Citation: JIANG Yan, WANG Xin, SUN Xiao-Qiang, WANG Yun-Xiang. Synthesis of a Chiral Ligand Containing 1,3,5-Triazine Unit[J]. Chinese Journal of Applied Chemistry, 2009, 26(11): 1371-1373.
Citation: JIANG Yan, WANG Xin, SUN Xiao-Qiang, WANG Yun-Xiang. Synthesis of a Chiral Ligand Containing 1,3,5-Triazine Unit[J]. Chinese Journal of Applied Chemistry, 2009, 26(11): 1371-1373.
一种含三嗪单元多齿手性配体的合成
摘要:
以(R,R)-1,2-二苯基乙二醇和氰尿酰氯为原料,经保护、醚化、去保护、取代等反应合成了一种新的手性多齿配体2-乙氧基-4-(2-甲氧基-乙氧基)-6-((1R,2R)-1,2-二苯基-2-甲氧基-乙氧基)-1,3,5-三嗪,并通过1H NMR、LCMS和元素分析测试技术对目标化合物的结构进行了表征。
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关键词:
- (R,R)-二苯基乙二醇
- / 氰尿酰氯
- / 手性多齿配体
English
Synthesis of a Chiral Ligand Containing 1,3,5-Triazine Unit
Abstract:
A novel chiral polydentate ligand,2-ethoxy-4-(2-methoxy-ethoxy)-6-((1R,2R)-1,2-diphenyl-2-methoxy-ethoxy)-1,3,5-triazine,was synthesized from(R,R)-hydrobenzoin and cyanuric chloride by means of functional group pretection,etherification,deprotection and substitution.The structure of the target product was characterized by 1H NMR,LCMS and elemental analysis.
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Key words:
- (R,R)-hydrobenzoin
- / cyanuric chloride
- / chiral polydentate ligand
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