引用本文:
顾建胜, 任志刚, 袁雅仙, 蒋嵘, 童剑英. Cu(Ⅰ)与2-甲基-3-丁炔-2-醇中性膦配合物的电化学合成[J]. 应用化学,
1999, 16(6): 95-97.
Citation: Gu Jiansheng, Ren Zhigang, Yuan Yaxian, Jiang Rong, Tong Jianying. Electrochemical Synthesis of Copper(Ⅰ) Complexes with 2-Methyl-3-butyn-2-of and Phosphines[J]. Chinese Journal of Applied Chemistry, 1999, 16(6): 95-97.
Citation: Gu Jiansheng, Ren Zhigang, Yuan Yaxian, Jiang Rong, Tong Jianying. Electrochemical Synthesis of Copper(Ⅰ) Complexes with 2-Methyl-3-butyn-2-of and Phosphines[J]. Chinese Journal of Applied Chemistry, 1999, 16(6): 95-97.
Cu(Ⅰ)与2-甲基-3-丁炔-2-醇中性膦配合物的电化学合成
English
Electrochemical Synthesis of Copper(Ⅰ) Complexes with 2-Methyl-3-butyn-2-of and Phosphines
Abstract:
The complexes of Cu with 2-methyl-3-butyn-2-ol(HL) and triphenylphosphine(pph3) or bis (diphenylphophine) methane (dppm) were prepared by an electrochemical method in nonaqueous solutions.The products were characterized by elemental analysis, IR, 1H and 13C NMR measurements as CuL, CuL·pph and CuL.dppm respectively.
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Key words:
- methyl-butynol
- / copper complex
- / electrochemical synthesis
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