引用本文:
张引, 高扬, 黄景琴, 陈文启. Eu(Ⅲ)、Tb(Ⅲ)双酞菁配合物的合成及其LB膜的荧光性[J]. 应用化学,
1999, 16(6): 33-36.
Citation: Zhang Yin, Gao Yang, Huanq Jinqqin, Chen Wenqi. Preparation of Tb(Ⅲ)/Eu(Ⅲ)-Bisphthalocyanine Complexes and the Fluorescence Bahavior of the LB Films Thereof[J]. Chinese Journal of Applied Chemistry, 1999, 16(6): 33-36.
Citation: Zhang Yin, Gao Yang, Huanq Jinqqin, Chen Wenqi. Preparation of Tb(Ⅲ)/Eu(Ⅲ)-Bisphthalocyanine Complexes and the Fluorescence Bahavior of the LB Films Thereof[J]. Chinese Journal of Applied Chemistry, 1999, 16(6): 33-36.
Eu(Ⅲ)、Tb(Ⅲ)双酞菁配合物的合成及其LB膜的荧光性
English
Preparation of Tb(Ⅲ)/Eu(Ⅲ)-Bisphthalocyanine Complexes and the Fluorescence Bahavior of the LB Films Thereof
Abstract:
Four complexes: Tb(Ⅲ)-octa-4-n-nonyloxyphthalocyanine (A),Eu(Ⅲ)-ocat-4-tetrehydrofurfuroxyphthalocyanine(B),Tb(Ⅲ)isphthalocyanine(C),Tb(Ⅲ)-ocia-4-nitrophthalocyanine(D) were synthesized and characterized by elemental analysis, IR, MS and UV-Vis spectra.The π-A isotherm data of B Indicates its good film-forming ability.The LB films of B formed on quarz by Y-type technique have good lumlnescence property, which is better with the thickness of the film. The films doped with o-phenanthroline(phen) show a great relative fluorescence in-tensity than purel,B films.Complex B with phen in molar ratio of 1：10 has best fluores-cence behavior.
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Key words:
- rate earth bisphthlocyanine complex
- / LB film
- / synthesis
- / fluorescence
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