引用本文:
毕先同, 朱道本, 叶成, 李素珍, 万梅香, 姚幼新, 钱人元. 哒嗪-碘电荷转移复合物的导电性[J]. 应用化学,
1990, 7(5): 68-71.
Citation: Bi Xiantong, Zhu Daoben, Ye Cheng, Li Suzhen, Wan Meixiang, Yao Youxin, Qian Renyuan. CONDUCTIVITY OF CHARGE TRANSFER COMPLEX OF PYRIDAZINE WITH IODINE[J]. Chinese Journal of Applied Chemistry, 1990, 7(5): 68-71.
Citation: Bi Xiantong, Zhu Daoben, Ye Cheng, Li Suzhen, Wan Meixiang, Yao Youxin, Qian Renyuan. CONDUCTIVITY OF CHARGE TRANSFER COMPLEX OF PYRIDAZINE WITH IODINE[J]. Chinese Journal of Applied Chemistry, 1990, 7(5): 68-71.
哒嗪-碘电荷转移复合物的导电性
English
CONDUCTIVITY OF CHARGE TRANSFER COMPLEX OF PYRIDAZINE WITH IODINE
Abstract:
The pyridazine-I2 charge transfer complexes have been found to have an electrical conductivity of 1-102 S/cm and a mixture of the complex with solid I2 up to 98% showed a conductivity greater than 1 S/cm. The voltage shorted compaction technique was used for the conductivity measurement. The complex sample showed a 20% increase in conductivity from room temperature to -30℃ and the value then decreases with further lowering the temperature to -10% of σRT at -100℃. XPS and laser Raman spectral data are also reported.
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Key words:
- pyridazine
- / charge transfer complex
- / conductivity
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